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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Lyons, Sean
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (36/36 displayed)
- 2024Response Surface Modelling Nafion-117 Sorption of Tetraammineplatinum(II) Chloride in the Electroless Plating of IPMCscitations
- 2021Stereolithography (SLA) utilised to print injection mould tooling in order to evaluate thermal and mechanical properties of commercial polypropylenecitations
- 2020Fused filament fabrication of peekcitations
- 2020Effect of electron beam irradiation on the rheological properties and phase transition temperature of poly(N-vinylcaprolactam)
- 2019Comparison of fused-filament fabrication to direct compression and injection molding in the manufacture of oral tabletscitations
- 2019Additive manufacturing of PLA/HNT nanocomposites for biomedical applicationscitations
- 2019Stability studies of hot-melt extruded ternary solid dispersions of poorly-water soluble indomethacin with poly(vinyl pyrrolidone-co-vinyl acetate)and polyethylene oxidecitations
- 2019Processing of nanocomposites using supercritical fluid assisted extrusion for stress/strain sensing applicationscitations
- 2019Influence of annealing and biaxial expansion on the properties of poly(l-lactic acid) medical tubingcitations
- 2019Faster release of lumen-loaded drugs than matrix-loaded equivalent in polylactic acid/halloysite nanotubescitations
- 20183D printed end of arm tooling (EOAT) of a robotic arm
- 2018Surface-modified halloysite nanotubes reinforced poly(lactic acid) for use in biodegradable coronary stentscitations
- 2018Material considerations for fused-filament fabrication of solid dosage formscitations
- 2018Investigation of miscibility estimation methods between indomethacin and poly(vinylpyrrolidone-co-vinyl acetate)citations
- 2018Degradable nanocomposites for fused filament fabrication applicationscitations
- 2017Halloysite nanotube reinforced polylactic acid compositecitations
- 2016The effect of the mixing routes of biodegradable polylactic acid and polyhydroxybutyrate nanocomposites and compatibilised nanocompositescitations
- 2014The effect of processing conditions for polylactic acid based fibre composites via twin-screw extrusioncitations
- 2014Effect of Compatibilizer Content on the Mechanical Properties of Bioplastic Composites via Hot Melt Extrusioncitations
- 2014Improvement in mechanical properties of grafted polylactic acid composite fibers via hot melt extrusioncitations
- 2014Melt Processing of Bioplastic Composites via Twin Screw Extrusion and Injection Moldingcitations
- 2013Mechanical and biodegradation performance of short natural fibre polyhydroxybutyrate compositescitations
- 2011Assessing the effect of selected photoinitiators on the properties of photopolymerised temperature sensitive hydrogels
- 2011Nano-enhanced food contact materials and the in vitro toxicity to human intestinal cells of nano-ZnO at low dose
- 2011Nano-enhanced food contanct materials and the in vitro toxicity to human intestinal cells of nano-ZnO at low dose.
- 2010Physical and mechanical properties of blends based on poly (dl-lactide), poly (l-lactide-glycolide) and poly (ε-caprolactone)citations
- 2010In vitro degradation and drug release from polymer blends based on poly(dl-lactide), poly(l-lactide-glycolide) and poly(ε-caprolactone)citations
- 2010Characterisation of the effects of a titanium micro particle filler on a polyether-block-amide host matrixcitations
- 2009Development and characterisation of an agar-polyvinyl alcohol blend hydrogelcitations
- 2008Characterisation and controlled drug release from novel drug-loaded hydrogelscitations
- 2008The significance of variation in extrusion speeds and temperatures on a PEO/PCL blend based matrix for oral drug deliverycitations
- 2007Preparation of monolithic matrices for oral drug delivery using a supercritical fluid assisted hot melt extrusion processcitations
- 2007The incorporation of an organically modified layered silicate in monolithic polymeric matrices produced using hot melt extrusioncitations
- 2007The synthesis, swelling behaviour and rheological properties of chemically crosslinked thermosensitive copolymers based on N-isopropylacrylamidecitations
- 2006The use of Agar as a novel filler for monolithic matrices produced using hot melt extrusioncitations
- 2006Lower critical solution temperature control and swelling behaviour of physically crosslinked thermosensitive copolymers based on N-isopropylacrylamidecitations
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article
Response Surface Modelling Nafion-117 Sorption of Tetraammineplatinum(II) Chloride in the Electroless Plating of IPMCs
Abstract
<p>This work looks at the effects of a varying concentration, soak time, pH and temperature on the sorption of tetraammineplatinum(II) chloride (Pt-Ammine) in Nafion-117 films in the context of the electroless plating of ionic polymer–metal composites (IPMCs). Sorption is characterised by atomic absorption spectroscopy. A definitive screening design carried out determined all four factors to be significant for further analysis using response surface modelling. A duplicated central composite design (CCD) was utilised to characterise how the four factors affect the sorption amount and efficiency. Regression models for both responses were of poor fit. Nevertheless, key insights were obtained on the effects of the process parameters on sorption behaviour. The results indicate that above 0.5 g/L Pt-Ammine sorption, the platinisation of 10 × 50 mm IPMC samples through sodium borohydride reduction becomes redundant by the surface resistance metric. IPMCs with surface resistance values of approximately 2.5 Ω/square were obtained through only one round of chemical reduction. Varying surface morphologies and electrode thicknesses were analysed under a scanning electron microscope. The CCD parameter settings were validated. Recommended settings for optimised Pt-Ammine sorption in 10 × 50 mm Nafion-117 films were identified as follows: 1.0 g/L Pt-Ammine concentration, 24 h soak time, pH of 3 and temperature of 20 °C.</p>