• Al-Helal, Kawther
• Scamans, Gm
• Fan, Zhongyun
• Chang, Ith
• Patel, Jb
• Gao, Feng
• Lázaro Nebreda, Jaime
• Stone, Ian

Abstract

Data Availability Statement: The data presented in this manuscript is available on request from the corresponding author. ; Copyright: © 2022 by the authors. The main problem of recycling aluminium scrap is the gradual accumulation of impurities, especially iron, which tend to form undesired intermetallic compounds that affect the integrity and the mechanical performance of the castings. In this paper, we aim to provide an overview on the topic of iron removal from aluminium melts through primary intermetallic precipitation and the progress made during the LiME Hub project to understand the process and to develop a more efficient procedure. We cover both thermodynamic analysis and experimental validation. We found that high shear melt conditioning technology enhances the typically slow nucleation and growth of the dense primary intermetallics, speeding up their sedimentation and allowing a faster removal of Fe from the melt by simple gravity sedimentation. It also promotes the formation of smaller and more compact Fe-rich intermetallics, allowing an increased volume fraction recovery and mitigating their effect of being present in the final castings. The technology is not limited to batch processing, with a 90% efficiency, but can also be applied to continuous melt treatment of aluminium scrap, with currently 60% efficiency, and could be combined with other solid–liquid separation techniques to increase the purification efficiency even more. ; EPSRC (UK) under grant number EP/N007638/1; European Commission under Grant No. 603577; Innovate UK under Project No.102797.

Topics

• impedance spectroscopy
• compound
• melt
• aluminium
• aluminium alloy
• precipitation
• casting
• iron
• intermetallic
• lime