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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Colbert, Declan Mary
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Publications (6/6 displayed)
- 2024Synthesis and characterization of 4D-printed NVCL-coDEGDA resin using stereolithography 3D printingcitations
- 2024Co-Optimization of Mechanical Properties and Radiopacity Through Radiopaque Filler Incorporation for Medical Tubing Applications
- 2023Effect of Mechanical Recycling on the Mechanical Properties of PLA-Based Natural Fiber-Reinforced Compositescitations
- 2023Micro-Injection Moulding of PEO/PCL Blend–Based Matrices for Extended Oral Delivery of Fenbendazolecitations
- 2023Compatibility Study Between Fenbendazole and Poly(Ethylene Oxide) with Application in Solid Dispersion Formulations Using Hot-Melt Extrusioncitations
- 2021Development of next generation polymer based long-term controlled release devices for improved animal health
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article
Effect of Mechanical Recycling on the Mechanical Properties of PLA-Based Natural Fiber-Reinforced Composites
Abstract
<jats:p>The present study investigates the feasibility of utilizing polylactic acid (PLA) and PLA-based natural fiber-reinforced composites (NFRCs) in mechanical recycling. A conical twin screw extrusion (CTSE) process was utilized to recycle PLA and PLA-based NFRCs consisting of 90 wt.% PLA and a 10 wt.% proportion of either basalt fibers (BFs) or halloysite nanotubes (HNTs) for up to six recycling steps. The recycled material was then injection molded to produce standard test specimens for impact strength and tensile property analysis. The mechanical recycling of virgin PLA led to significant discoloration of the polymer, indicating degradation during the thermal processing of the polymer due to the formation of chromatophores in the structure. Differential scanning calorimetry (DSC) analysis revealed an increase in glass transition temperature (Tg) with respect to increased recycling steps, indicating an increased content of crystallinity in the PLA. Impact strength testing showed no significant detrimental effects on the NFRCs’ impact strength up to six recycling steps. Tensile testing of PLA/HNT NFRCs likewise did not show major decreases in values when tested. However, PLA/BF NFRCs exhibited a significant decrease in tensile properties after three recycling steps, likely due to a reduction in fiber length beyond the critical fiber length. Scanning electron microscopy (SEM) of the fracture surface of impact specimens revealed a decrease in fiber length with respect to increased recycling steps, as well as poor interfacial adhesion between BF and PLA. This study presents a promising initial view into the mechanical recyclability of PLA-based composites.</jats:p>