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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Willför, Stefan
Åbo Akademi University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (24/24 displayed)
- 2022Injectable thiol-ene hydrogel of galactoglucomannan and cellulose nanocrystals in delivery of therapeutic inorganic ions with embedded bioactive glass nanoparticlescitations
- 2022Injectable thiol-ene hydrogel of galactoglucomannan and cellulose nanocrystals in delivery of therapeutic inorganic ions with embedded bioactive glass nanoparticlescitations
- 2022The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acids
- 2022Digital light processing (DLP) 3D-fabricated antimicrobial hydrogel with a sustainable resin of methacrylated woody polysaccharides and hybrid silver-lignin nanospherescitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose SurfaceviaOne-Pot Water-Phase Synthesiscitations
- 2021Bio-Based Hydrogels With Ion Exchange Properties Applied to Remove Cu(II), Cr(VI), and As(V) Ions From Watercitations
- 2021Removal of nafcillin sodium monohydrate from aqueous solution by hydrogels containing nanocellulosecitations
- 2021On Laccase-Catalyzed Polymerization of Biorefinery Lignin Fractions and Alignment of Lignin Nanoparticles on the Nanocellulose Surface via One-Pot Water-Phase Synthesiscitations
- 2021Removal of nafcillin sodium monohydrate from aqueous solution by hydrogels containing nanocellulose:An experimental and theoretical studycitations
- 2020Tailored thermosetting wood adhesive based on well-defined hardwood lignin fractionscitations
- 2020The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acidscitations
- 2020Larch wood residues valorization through extraction and utilization of high value-added productscitations
- 2019The Hydrophobicity of Lignocellulosic Fiber Network Can Be Enhanced with Suberin Fatty Acidscitations
- 2018Novel biorenewable composite of wood polysaccharide and polylactic acid for three dimensional printingcitations
- 2017Mild oxalic-acid-catalyzed hydrolysis as a novel approach to prepare cellulose nanocrystalscitations
- 2016Softwood-based sponge gelscitations
- 2016Development of nanocellulose scaffolds with tunable structures to support 3D cell culturecitations
- 2015Tailor-made hemicellulose-based hydrogels reinforced with nanofibrillated cellulosecitations
- 2015Composite films of nanofibrillated cellulose and O-acetyl galactoglucomannan (GGM) coated with succinic esters of GGM showing potential as barrier material in food packagingcitations
- 2014Impact of torrefaction on the chemical structure of birch woodcitations
- 2011Oxidation of lignans and lignin model compounds by laccase in aqueous solvent systemscitations
- 2010Comparison of microencapsulation properties of spruce galactoglucomannans and arabic gum using a model hydrophobic core compoundcitations
- 2008Films from spruce galactoglucomannan blended with poly(vinyl alcohol), corn arabinoxylan, and konjac glucomannan
- 2008Kinetics of acid hydrolysis of water-soluble spruce O-acetyl galactoglucomannanscitations
Places of action
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article
Bio-Based Hydrogels With Ion Exchange Properties Applied to Remove Cu(II), Cr(VI), and As(V) Ions From Water
Abstract
Hydrogels with ion exchange properties were synthesized from compounds derived from wood biopolymer hemicellulose and from commercial vinyl monomers to be tested as active materials for the removal of Cu(II), Cr(VI), and As(V) ions. The hemicellulose O-acetyl galactoglucomannan (GGM) was used as the precursor material, and through a transesterification reaction, GGM was converted into a macromonomer GGM–glycidyl methacrylate (GGM-GMA). Subsequently, the GGM-GMA macromonomer, containing more than one methacrylate group, was used as a crosslinking agent in the synthesis of hydrogels through free-radical polymerization reactions in combination with a 2-acrylamido-2-methyl-1-propanesulfonic acid monomer to produce a cation exchange hydrogel. Also, (3-acrylamidopropyl)trimethylammonium chloride monomer was applied together with the GGM-GMA to form hydrogels that can be used as anion exchange hydrogel. The hydrogels were characterized by Fourier transform-infrared (FT-IR), 1 H-NMR spectroscopy, and thermogravimetric analysis (TGA), as well as derivative thermogravimetry (DTG). The microstructure of the hydrogels was characterized by scanning electron microscopy (SEM) analysis with X-ray microanalysis energy-dispersive spectroscopy (EDS). The results obtained regarding the absorption capacity of the Cu(II), Cr(VI), and As(V) ions were studied as a function of the pH value and the initial concentration of the metal ions in the solutions. Absorption was carried out in consecutive batches, and it was found that the poly(GGM-GMA/AMPSH) hydrogel reached an absorption capacity of 90 mg g –1 for Cu(II). The poly(GGM-GMA/APTACl) hydrogel reached values of 69 and 60 mg g –1 for Cr(VI) and As(V) oxyanions, respectively. Tests with polymer blends (mixtures of anionic and cationic hydrogels) were also carried out to remove Cu(II), Cr(VI), and As(V) ions from multi-ionic solutions, obtaining satisfactory results.