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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Tachibana, Yasuhiro
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2022Tantalum Oxide as an Efficient Alternative Electron Transporting Layer for Perovskite Solar Cellscitations
- 2022Photo-Induced Charge Carrier Dynamics of Metal Halide Perovskite
- 2020The Performance-Determining Role of Lewis Bases in Dye-Sensitized Solar Cells Employing Copper-Bisphenanthroline Redox Mediatorscitations
- 2018Identifying an Optimum Perovskite Solar Cell Structure by Kinetic Analysiscitations
- 2018Excitation wavelength dependent interfacial charge transfer dynamics in a CH3NH3PbI3 perovskite filmcitations
- 2017Fluorene-Thiophene Copolymer Wire on TiO2citations
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article
Excitation wavelength dependent interfacial charge transfer dynamics in a CH3NH3PbI3 perovskite film
Abstract
<p>Elucidation of interfacial charge separation and recombination mechanisms is crucial to improve performance of organic-inorganic metal halide perovskite solar cells. Here, we have investigated influence of initially populated electron and hole potential levels in a perovskite conduction band (CB) and valence band (VB), respectively, by altering an excitation wavelength on interfacial charge separation and recombination dynamics in a CH<sub>3</sub>NH<sub>3</sub>PbI<sub>3</sub> perovskite film sandwiched by a mesoporous TiO<sub>2</sub> structure as an electron transport material (ETM) and a spiro-OMeTAD film as a hole transport material (HTM). Multi-phasic electron injection reactions are observed over <1.2 to several tens of nanoseconds, while most of holes are injected to a spiro-OMeTAD layer within the transient emission spectroscopy instrument response time (1.2 ns). In contrast, interfacial charge recombination rates are slower (from 5 ms to 1.3 s) with the increase of the excitation wavelength. These kinetics suggest that as long as low excitation intensity is employed, e.g. 10 nJ/cm<sup>2</sup> or 1 sun (100 mW/cm<sup>2</sup>), the APCE of ~100% can be expected at any excitation wavelength for the solar cells based on FTO/c-TiO<sub>2</sub>/m-TiO<sub>2</sub>/MAPbI<sub>3</sub>/OMeTAD films.</p>