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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Miyayama, Masaru
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2012High capacity positive electrodes for secondary Mg-ion batteriescitations
- 2012Synthesis and electrochemical behavior of hollandite MnO2/acetylene black composite cathode for secondary Mg-ion batteriescitations
- 2011The diffusions and associated interfacial layer formation between thin film electrolyte and cermet anode in IT-SOFCcitations
- 2011Diffusion and segregation along grain boundary at the electrolyte–anode interface in IT-SOFCcitations
- 2011Mutual diffusion and microstructure evolution at the electrolyte−anode interface in intermediate temperature solid oxide fuel cellcitations
- 2007Cathode performance of nanostructured La1-aSraCo1-bFebO3- on a Ce0.8Sm0.2O2 electrolyte prepared by citrate-nitrate auto-combustioncitations
- 2006Electrode performance of nanostructured La1-aSraCo1-bFebO3-x on a Ce0.8Sm0.2O2 electrolyte prepared by citrate nitrate auto-combustioncitations
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article
Cathode performance of nanostructured La1-aSraCo1-bFebO3- on a Ce0.8Sm0.2O2 electrolyte prepared by citrate-nitrate auto-combustion
Abstract
Nanostructured La1−aSraCo1−bFebO3−x a = 0.3–0.5; b = 0–0.2 and Ce0.8Sm0.2O2 powders were successfully prepared by citratenitrate autocombustion synthesis and were characterized by scanning electron microscopy and X-ray diffraction analysis. Electrochemical impedance spectroscopy measurements on symmetric cells were performed to evaluate the applicability of La1−aSraCo1−bFebO3−x as a cathode material for intermediate temperature solid oxide fuel cells based on Sm doped-ceria electrolytes. Our results demonstrated that strontium has a positive effect while iron shows a slightly negative effect on the interfacial resistance. The effect of the electrode sintering temperature was investigated by varying the temperature from 850 to 1250°C, and the best sintering temperature was found to be 900°C. The best characteristics as cathode at intermediate operating temperatures were found for the composition with a = 0.4 and the minimum iron doping, b = 0.05; at 700°C, an area specific resistance of 0.13cm2 was measured. © 2006 The Electrochemical Society