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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Mottura, Alessandro
University of Birmingham
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (15/15 displayed)
- 2024First-principles calculations of intrinsic stacking fault energies and elastic properties in binary nickel alloyscitations
- 2018First-principles modeling of superlattice intrinsic stacking fault energies in Ni3Al based alloys
- 2018First-principles modeling of the temperature dependence for the superlattice intrinsic stacking fault energies in L12 Ni75-xXxAl25 alloyscitations
- 2018A kinetic Monte Carlo study of vacancy diffusion in non-dilute Ni-Re alloyscitations
- 2017First-principles calculations of thermodynamic properties and planar fault energies in Co3X and Ni3X L12 compoundscitations
- 2016Alloys-by-designcitations
- 2015High resolution energy dispersive spectroscopy mapping of planar defects in L12-containing Co-base superalloyscitations
- 2014Three-dimensional characterization of the permeability of W–Cu composites using a new “TriBeam” techniquecitations
- 2014Can slow-diffusing solute atoms reduce vacancy diffusion in advanced high-temperature alloys?citations
- 2014Nickel-rhenium compound sheds light on the potency of rhenium as a strengthener in high-temperature nickel alloyscitations
- 2014Modelling of the influence of alloy composition on flow stress in high-strength nickel-based superalloyscitations
- 2012A first-principles study of the effect of Ta on the superlattice intrinsic stacking fault energy of L12-Co3(Al,W)citations
- 2010Atom probe tomography analysis of the distribution of rhenium in nickel alloyscitations
- 2010Analysis of atomic-scale phenomena and the rhenium effect in nickel superalloys
- 2008A critique of rhenium clustering in Ni-Re alloys using extended X-ray absorption spectroscopycitations
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article
Nickel-rhenium compound sheds light on the potency of rhenium as a strengthener in high-temperature nickel alloys
Abstract
For many decades, it has been known that rhenium imparts a tremendous resistance to creep to the nickel-based high-temperature alloys colloquially known as superalloys. This effect is so pronounced that is has been dubbed “the rhenium effect.” Its origins are ill-understood, even though it is so critical to the performance of these high-temperature alloys. In this paper we show that the currently known phase diagram is inaccurate, and neglects a stoichiometric compound at 20 at.% Re (Ni<sub>4</sub>Re). The presence of this precipitate at low temperatures and the short-range ordering of Re in fcc-Ni observed at higher temperatures have important ramifications for the Ni-based superalloys. The Ni<sub>4</sub>Re compound is shown to be stable by quantum mechanical high-throughput calculations at 0 K. Monte Carlo simulations show that it is thermally persistent up to ≈930 K when considering configurational entropy. The existence of this compound is investigated using extended x-ray absorption fine spectroscopy on a Ni<sub>96.62</sub>Re<sub>3.38</sub> alloy.