| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Salmon, Philip Stephen
University of Bath
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (17/17 displayed)
- 2024Pressure dependent structure of amorphous magnesium aluminosilicatescitations
- 2023Mapping the structural trends in zinc aluminosilicate glassescitations
- 2022Structure and related properties of amorphous magnesium aluminosilicatescitations
- 2021Structure of crystalline and amorphous materials in the NASICON system Na1+xAlxGe2- x(PO4)3citations
- 2019Ordering on different length scales in liquid and amorphous materialscitations
- 2019Structure of the intermediate phase glasses GeSe3 and GeSe4citations
- 2017Topological Ordering and Viscosity in the Glass-Forming Ge-Se System: The Search for a Structural or Dynamical Signature of the Intermediate Phasecitations
- 2017Structure of rare-earth chalcogenide glasses by neutron and x-ray diffractioncitations
- 2016Pressure-driven transformation of the ordering in amorphous network-forming materialscitations
- 2015Networks under pressurecitations
- 2015Pressure-dependent structure of the null-scattering alloy Ti0.676Zr0.324citations
- 2013Fragile glass - formers reveal their structural secrets
- 2013Identifying and characterising the different structural length scales in liquids and glasses: an experimental approachcitations
- 2011Structure of eutectic liquids in the Au-Si, Au-Ge, and Ag-Ge binary systems by neutron diffractioncitations
- 2010Structure of liquid and glassy ZnCl2citations
- 2009Atomic structure of the two intermediate phase glasses SiSe4 and GeSe4citations
- 2003Identification of the relative distribution of rare-earth ions in phosphate glassescitations
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article
Structure of liquid and glassy ZnCl2
Abstract
The method of isotope substitution in neutron diffraction was used to measure the structure of liquid ZnCl2 at 332(5) degrees C and glassy ZnCl2 at 25(1) degrees C. The partial structure factors were obtained from the measured diffraction patterns by using the method of singular value decomposition and by using the reverse Monte Carlo procedure. The partial structure factors reproduce the diffraction patterns measured by high-energy x-ray diffraction once a correction for the resolution function of the neutron diffractometer has been made. The results show that the predominant structural motif in both phases is the corner sharing ZnCl4 tetrahedron and that there is a small number of edge-sharing configurations, these being more abundant in the liquid. The tetrahedra organize on an intermediate length scale to give a first sharp diffraction peak in the measured diffraction patterns at a scattering vector k(FSDP) similar or equal to 1 angstrom(-1) that is most prominent for the Zn-Zn correlations. The results support the notion that the relative fragility of tetrahedral glass forming MX2 liquids is related to the occurrence of edge-sharing units.