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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Azadmanjiri, Jalal
University of Chemistry and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Reaction mechanism and performance of innovative 2D germanane‐silicane alloys: SixGe1−xH electrodes in lithium‐ion batteriescitations
- 20242D Rhenium- and Niobium-Doped WSe 2 Photoactive Cathodes in Photo-Enhanced Hybrid Zn-Ion Capacitorscitations
- 2022Two-dimensional layered chromium selenophosphate: advanced high-performance anode material for lithium-ion batteriescitations
- 2022Universal Capacitance Boost—Smart Surface Nanoengineering by Zwitterionic Molecules for 2D MXene Supercapacitorcitations
- 2021Functionalized germanane/SWCNT hybrid films as flexible anodes for lithium-ion batteriescitations
- 2012The use of plasma treatment for simultaneous carbonization and reduction of iron oxide/polypyrrole core/shell nanoparticlescitations
- 2012Phase reduction of coated maghemite (γ-Fe2O3) nanoparticles under microwave-induced plasma heating for rapid heat treatmentcitations
- 2011Synthesis and electromagnetic interference shielding properties of iron oxide/polypyrrole nanocompositescitations
- 2009Potential blends of magnetic nano-composites for EMI shielding applications
Places of action
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article
Two-dimensional layered chromium selenophosphate: advanced high-performance anode material for lithium-ion batteries
Abstract
The demands of the energy storage market for better performing lithium-ion batteries (LIBs) are enormous and ever-increasing. Following this trend, new electrode materials with higher energy and power densities should be developed to reach the electrode requirements of next-generation batteries. With this in mind, we present a novel composite (CrPSe3-G-MWCNT@NiB) that combines diverse characteristics of the excellent Li storage properties of 2D layered chromium selenophosphate (CrPSe3), the high conductivity and specific surface area of carbon-based materials [graphite (G) and multi-walled carbon nanotubes (MWCNTs)], and the abundant coordinative unsaturated sites of Ni-B nanoflakes. The composites were synthesized via a process involving three stages: (a) a one-step high-temperature solid-phase 2D CrPSe3 preparation, (b) high-energy ball milling integration with the carbon materials, and (c) a fast interface chemical reduction coating with the Ni-B nanoflakes. It is demonstrated that the optimized CrPSe3-G-MWCNT@NiB composites exhibit a remarkable electrochemical response in lithium half-cells, delivering around 657 mAh g(-1) after 200 cycles, as well as a significantly longer cycle life, higher rate capability and lower charge/discharge polarization in comparison with the bulk CrPSe3. Galvanostatic studies also revealed that the CrPSe3-G-MWCNTs@NiB electrode displays a remarkable electrochemical property, which enable its application in lithium full cells, with a capacity of 123 mAh g(cathode) (-1) after 40 cycles and a high Coulombic efficiency (over 99.1%). Thus, the integration of the carbon materials and Ni-B nanoflakes into the presented composite makes it a particularly promising candidate anode for use in high performance LIBs.