| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Palstra, Thomas T. M.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2019Electronic mobility and crystal structures of 2,5-dimethylanilinium triiodide and tin-based organic-inorganic hybrid compoundscitations
- 2018Micropatterned 2D Hybrid Perovskite Thin Films with Enhanced Photoluminescence Lifetimescitations
- 2018Micropatterned 2D Hybrid Perovskite Thin Films with Enhanced Photoluminescence Lifetimescitations
- 2018Magnetic functionality of thin film perovskite hybridscitations
- 2018Out-of-plane polarization in a layered manganese chloride hybridcitations
- 2016Band gap narrowing of Sns2 superstructures with improved hydrogen productioncitations
- 2016Crystallite size dependence of thermoelectric performance of CuCrO2citations
- 2016Confinement Effects in Low-Dimensional Lead Iodide Perovskite Hybridscitations
- 2016Band gap narrowing of SnS2 superstructures with improved hydrogen productioncitations
- 2015Effect of Vacancies on Magnetism, Electrical Transport, and Thermoelectric Performance of Marcasite FeSe2-delta (delta=0.05)citations
- 2015Effect of Vacancies on Magnetism, Electrical Transport, and Thermoelectric Performance of Marcasite FeSe2-delta (delta=0.05)citations
- 2014High-Purity Fe3S4 Greigite Microcrystals for Magnetic and Electrochemical Performancecitations
- 2014High-Purity Fe3S4 Greigite Microcrystals for Magnetic and Electrochemical Performancecitations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2014Self-Assembly of Ferromagnetic Organic–Inorganic Perovskite-Like Filmscitations
- 2013Excess manganese as the origin of the low-temperature anomaly in NiMnSbcitations
- 2012Spin-lattice coupling in iron jarositecitations
- 2010A two-dimensional magnetic hybrid material based on intercalation of a cationic Prussian blue analog in montmorillonite nanoclaycitations
- 2010Controlled tunnel-coupled ferromagnetic electrodes for spin injection in organic single-crystal transistorscitations
- 2009Competition between Jahn-Teller coupling and orbital fluctuations in HoVO3citations
- 2008Magnetic and dielectric properties of YbMnO(3) perovskite thin filmscitations
- 2008Magnetoelectric coupling in the cubic ferrimagnet Cu(2)OSeO(3)citations
- 2007Experimental evidence for an intermediate phase in the multiferroic YMnO3citations
- 2007Experimental evidence for an intermediate phase in the multiferroic YMnO3citations
- 2007Crystal growth, structure, and electronic band structure of tetracene-TCNQcitations
- 2007Competing orbital ordering in RVO(3) compoundscitations
- 2006Experimental evidence for an intermediate phase in the multiferroic YMnO3citations
- 2006Carbon nanotubes encapsulating superconducting single-crystalline tin nanowirescitations
- 2003Identification of polymorphs of pentacenecitations
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article
Out-of-plane polarization in a layered manganese chloride hybrid
Abstract
We investigate possible mechanisms to induce electric polarization in layered organic-inorganic hybrids. Specifically, we investigate the structural phase transitions of PEA(2)MnCl(4) (PEA = phenethylamine) using temperature dependent single-crystal X-ray diffraction analysis, including the symmetry analysis of the observed space groups. Our results show that PEA(2)MnCl(4) transforms from a high-temperature centrosymmetric structure with space group I4/mmm to a low-temperature polar Pca2(1) phase via an intermediate phase with polar space group Aea2. We study the mechanism responsible for the I4/mmm to Aea2 polar phase transition and find that it is different from previously proposed mechanisms in similar systems. The transition is governed by the opening of a small dihedral angle between the phenyl ring planes of two adjacent PEA molecules, which consequently become crystallographically inequivalent in the Aea2 phase. This molecular rotation induces a significant difference in the lengths of the ethylammonium tails of the two molecules, which coordinate the inorganic layer asymmetrically and are consequently involved in different hydrogen bonding patterns. Consequently, the negatively charged chlorine octahedron that coordinates the Mn(2+)cation deforms. This deformation moves the Mn2+ off-center along the out-of-plane-axis, contributing to the polar nature of the structure. Notably, the polar axis is out-of-plane with respect to the inorganic sheets. This is in contrast to other layered organic-inorganic hybrids as well as conventional layered perovskites, such as the Aurivillius phases, where in-plane polarization is observed. Our findings add to the understanding of possible mechanisms that can induce ferroelectric behavior in layered organic-inorganic hybrids. (C) 2018 Author(s).