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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Niss, Kristine
Roskilde University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Piezoelectric shear rheometrycitations
- 2018High-pressure cell for simultaneous dielectric and neutron spectroscopycitations
- 2017Coupling between Molecular Mobility and Kinetics of Crystal Growth in a Hydrogen-Bonded Liquidcitations
- 2017Connection between fragility, mean-squared displacement and shear modulus in two van der Waals bonded glass-forming liquidscitations
- 2015Communication: High pressure specific heat spectroscopy reveals simple relaxation behavior of glass forming molecular liquidcitations
- 2014The dynamic bulk modulus of three glass-forming liquidscitations
- 2005Dielectric and shear mechanical relaxations in glass-forming liquidscitations
Places of action
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article
High-pressure cell for simultaneous dielectric and neutron spectroscopy
Abstract
In this article, we report on the design, manufacture, and testing of a high-pressure cell for simultaneous dielectric and neutron spectroscopy. This cell is a unique tool for studying dynamics on different time scales, from kilo- to picoseconds, covering universal features such as the α relaxation and fast vibrations at the same time. The cell, constructed in cylindrical geometry, is made of a high-strength aluminum alloy and operates up to 500 MPa in a temperature range between roughly 2 and 320 K. In order to measure the scattered neutron intensity and the sample capacitance simultaneously, a cylindrical capacitor is positioned within the bore of the high-pressure container. The capacitor consists of two concentric electrodes separated by insulating spacers. The performance of this setup has been successfully verified by collecting simultaneous dielectric and neutron spectroscopy data on dipropylene glycol, using both backscattering and time-of-flight instruments. We have carried out the experiments at different combinations of temperature and pressure in both the supercooled liquid and glassy state.