| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Silva, Er
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2022Antifouling Marine Coatings with a Potentially Safer and Sustainable Synthetic Polyphenolic Derivativecitations
- 2022Cyclam-based iron(iii) and copper(ii) complexes: synthesis, characterization and application as antifungal agentscitations
- 2021Assessment of the environmental compatibility and antifouling performance of an innovative biocidal and foul-release multifunctional marine coatingcitations
- 2020Experimental Assessment of the Performance of Two Marine Coatings to Curb Biofilm Formation of Microfoulerscitations
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article
Cyclam-based iron(iii) and copper(ii) complexes: synthesis, characterization and application as antifungal agents
Abstract
New cyclam-based complexes of formulae [{H-2(4-CF3PhCH2)(2)Cyclam}FeCl2]Cl and [{H-2(4-CF3PhCH2)(2)Cyclam}Cu](CH3COO)(2)center dot 2H(2)O were synthesized, in very high yields, by the reaction of H-2(4-CF3PhCH2)(2)Cyclam with the corresponding metal salts in methanol. [{H-2(4-CF3PhCH2)(2)Cyclam}FeCl2]Cl was also prepared, quantitatively, in the solid state by mechanochemistry. The Mossbauer spectra of [{H-2(4-CF3PhCH2)(2)Cyclam}FeCl2]Cl show that the high-spin cis complex is the major product of both reactions. The EPR data of [{H-2(4-CF3PhCH2)(2)Cyclam}Cu](CH3COO)(2)center dot 2H(2)O are consistent with two distinct Cu2+ species, whose solid state molecular structures were determined by single crystal X-ray diffraction and correspond to complexes displaying octahedral and square-pyramidal geometries. The screening of the antifungal activity of both metal complexes revealed the higher activity of [{H-2(4-CF3PhCH2)(2)Cyclam}FeCl2]Cl to inhibit the growth of unicellular and multicellular fungal species with described pathogenic potential.