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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Rasul, Shahid
Northumbria University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (18/18 displayed)
- 2024Shaping sustainable pathwayscitations
- 2024Enhancing lithium-ion battery anode performance via heterogeneous nucleation of silver within Ti3C2-MXene frameworkscitations
- 2024Innovative Tin and hard carbon architecture for enhanced stability in lithium-ion battery anodescitations
- 2024Sputtered Hard Carbon for High-Performance Energy Storage Batteries
- 2024Designing Molybdenum Trioxide and Hard Carbon Architecture for Stable Lithium‐Ion Battery Anodescitations
- 2023Multi-layered Sn and Hard Carbon Architectures for Long-Term Stability and High-Capacity Lithium-Ion Battery Anodes
- 2023Fabrication of WO3 / Fe 2 O 3 heterostructure photoanode by PVD for photoelectrochemical applicationscitations
- 2023Advancing Lithium-Ion Battery Anodes: Novel Sn and Hard Carbon Architectures for Long-Term Stability and High Capacity
- 2023Molybdenum Incorporated O3‐type Sodium Layered Oxide Cathodes for High‐Performance Sodium‐Ion Batteriescitations
- 2022Coal fly ash supported CoFe2O4 nanocompositescitations
- 2021Enhancement of mechanical and corrosion resistance properties of electrodeposited Ni–P–TiC composite coatingscitations
- 2021In Situ Printing and Functionalization of Hybrid Polymer-Ceramic Composites Using a Commercial 3D Printer and Dielectrophoresis—A Novel Conceptual Designcitations
- 2021In situ printing and functionalization of hybrid polymer-ceramic composites using a commercial 3d printer and dielectrophoresis—a novel conceptual designcitations
- 2016Characterization of a porous carbon material functionalized with cobalt-oxide/cobalt core-shell nanoparticles for lithium ion battery electrodes
- 2016A simple UV-ozone surface treatment to enhance photocatalytic performance of TiO 2 loaded polymer nanofiber membranescitations
- 2014Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel productioncitations
- 2012High capacity positive electrodes for secondary Mg-ion batteriescitations
- 2012Synthesis and electrochemical behavior of hollandite MnO2/acetylene black composite cathode for secondary Mg-ion batteriescitations
Places of action
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article
Photoelectrochemical and electrocatalytic properties of thermally oxidized copper oxide for efficient solar fuel production
Abstract
We report the use of a facile and highly scalable synthesis process to control growth products of earth-abundant Cu-based oxides and their application in relevant photoelectrochemical and electrochemical solar fuel generation systems. Characterization of the synthesized Cu(I)/Cu(II) oxides indicates that their surface morphology and chemical composition can be simply tuned by varying two synthesis parameters (time and temperature). UV-Vis spectroscopy and impedance spectroscopy studies are performed to estimate the band structures and electronic properties of these p-type semiconductor materials. Photoelectrodes made of Cu oxides possess favorable energy band structures for production of hydrogen from water; the position of their conduction band is ≈1 V more negative than the water-reduction potential. High acceptor concentrations on the order of 1018-1019 cm-3 are obtained, producing large electric fields at the semiconductor-electrolyte interface and thereby enhancing charge separation. The highly crystalline pristine samples used as photocathodes in photoelectrochemical cells exhibit high photocurrents under AM 1.5G simulated illumination. When the samples are electrochemically reduced under galvanostatic conditions, the co-existence of the oxide with metallic Cu on the surface seems to function as an effective catalyst for the selective electrochemical reduction of CO2. © the Partner Organisations 2014.