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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Paineau, Erwan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2024Re-entrant phase transitions in Laponite/Gum Arabic nanocomposites
- 2024β-cyclodextrin and carbonyl iron-based supramolecular gels: microstructure and magnetorheology
- 2024Structural Properties and Photocatalytic Activity of TiO 2 /Au Nanocomposites Synthesized with Glucosecitations
- 2024Impact of aluminium and gallium substitutions on the ferrihydrite and goethite structure: Consequences for rare earth element adsorption and complexationcitations
- 2024The Rheological and Structural Properties of Aqueous Graphene Oxide Dispersions: Concentration and pH Dependencecitations
- 2024Investigating the phase behaviour of binary suspensions of cellulose nanocrystals and montmorillonite with nonlinear rheology, SAXS and polarized optical microscopycitations
- 2020Influence of the Al/Ge Ratio on the Structure and Self-Organization of Anisometric Imogolite Nanotubescitations
- 2019Photonic titanium dioxide film obtained from hard template with chiral nematic structure for environmental applicationcitations
- 2019Nanomaterials From Imogolite: Structure, Properties, and Functional Materialscitations
- 2018Swelling Inhibition of Liquid Crystalline Colloidal Montmorillonite and Beidellite Clays by DNAcitations
- 2018Imogolite Nanotubes: A Flexible Nanoplatform with Multipurpose Applicationscitations
- 2016A liquid-crystalline hexagonal columnar phase in highly-dilute suspensions of imogolite nanotubescitations
- 2013Intracellular fate of carbon nanotubes inside murine macrophages: pH-dependent detachment of iron catalyst nanoparticles.citations
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article
A liquid-crystalline hexagonal columnar phase in highly-dilute suspensions of imogolite nanotubes
Abstract
Liquid crystals have found wide applications in many fields ranging from detergents to information displays and they are also increasingly being used in the 'bottom-up' self-assembly approach of material nano-structuration. Moreover, liquid-crystalline organizations are frequently observed by biologists. Here we show that one of the four major lyotropic liquid-crystal phases, the columnar one, is much more stable on dilution than reported so far in literature. Indeed, aqueous suspensions of imogolite nanotubes, at low ionic strength, display the columnar liquid-crystal phase at volume fractions as low as B0.2%. Consequently, due to its low visco-elasticity, this columnar phase is easily aligned in an alternating current electric field, in contrast with usual columnar liquid-crystal phases. These findings should have important implications for the statistical physics of the suspensions of charged rods and could also be exploited in materials science to prepare ordered nanocomposites and in biophysics to better understand solutions of rod-like biopolymers.