• Denayer, Joeri F. M.
• Waroquier, Michel
• Vandichel, Matthias
• Voort, Pascal Van Der
• Biswas, Shyam
• Verstraelen, Toon
• Liu, Ying-Ya
• Couck, Sarah
• Leus, Karen
• Speybroeck, Veronique Van
• Vanpoucke, Danny E. P.

Abstract

<p>Six new functionalized vanadium hydroxo terephthalates [V-III(OH)(BDC-X)]center dot n(guests) (MIL-47(V-III)-X-AS) (BDC = 1,4-benzenedicarboxylate; X = -Cl, -Br, -CH3, -CF3, -OH, -OCH3; AS = as-synthesized) along with the parent MIL-47 were synthesized under rapid microwave-assisted hydrothermal conditions (170 degrees C, 30 min, 150 W). The unreacted H2BDC-X and/or occluded solvent molecules can be removed by thermal activation under vacuum, leading to the empty-pore forms of the title compounds (MIL-47(V-IV)-X). Except pristine MIL-47 (+III oxidation state), the vanadium atoms in all the evacuated functionalized solids stayed in the +IV oxidation state. The phase purity of the compounds was ascertained by X-ray powder diffraction (XRPD), diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy, Raman, thermogravimetric (TG), and elemental analysis. The structural similarity of the filled and empty-pore forms of the functionalized compounds with the respective forms of parent MIL-47 was verified by cell parameter determination from XRPD data. TGA and temperature-dependent XRPD (TDXRPD) experiments in an air atmosphere indicate high thermal stability in the 330-385 degrees C range. All the thermally activated compounds exhibit significant microporosity (S-BET in the 305-897 m(2) g(-1) range), as verified by the N-2 and CO2 sorption analysis. Among the six functionalized compounds, MIL-47(V-IV)-OCH3 shows the highest CO2 uptake, demonstrating the determining role of functional groups on the CO2 sorption behavior. For this compound and pristine MIL-47(V-IV), Widom particle insertion simulations were performed based on ab initio calculated crystal structures. The theoretical Henry coefficients show a good agreement with the experimental values, and calculated isosurfaces for the local excess chemical potential indicate the enhanced CO2 affinity is due to two effects: (i) the interaction between the methoxy group and CO2 and (ii) the collapse of the MIL-47(V-IV)-OCH3 framework.</p>

Topics

• impedance spectroscopy
• pore
• compound
• phase
• experiment
• simulation
• thermogravimetry
• activation
• vanadium
• elemental analysis