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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Shirzadi, Amir A.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (21/21 displayed)
- 2020Diffusion bonding of TiC or TiB reinforced Ti–6Al–4V matrix composites to conventional Ti–6Al–4V alloycitations
- 2019Development of Auto Ejection Melt Spinning (AEMS) and its application in fabrication of cobalt-based ribbonscitations
- 2019Layered Structures of Ti-6Al-4V Alloy and Metal Matrix Composites on Its Base Joint by Diffusion Bonding and Friction Weldingcitations
- 2019Modelling and design of new stainless-steel welding alloys suitable for low-deformation repairs and restoration processescitations
- 2019Mechanical Properties and Processing Techniques of Bulk Metal–Organic Framework Glassescitations
- 2019A new method for liquid-phase bonding of copper plates to aluminum nitride (AlN) substrates used in high-power modulescitations
- 2018Gallium-assisted diffusion bonding of stainless steel to titanium; microstructural evolution and bond strengthcitations
- 2016Effect of Cu addition on microstructure and impact toughness in the simulated coarse-grained heat-affected zone of high-strength low-alloy steelscitations
- 2015Microstructure and Interfacial Reactions During Vacuum Brazing of Stainless Steel to Titanium Using Ag-28 pct Cu Alloycitations
- 2015Austenite memory and variant selection in a novel martensitic welding alloycitations
- 2013Microstructure and interfacial reactions during active metal brazing of stainless steel to titaniumcitations
- 2012Effect of SiC reinforcement particles on the grain density in a magnesium-based metal-matrix composite: modelling and experimentcitations
- 2012Crystallization model of magnesium primary phase in the AZ91/SiC compositecitations
- 2011Combined effect of stress and strain on crystallographic orientation of bainite
- 2011Design of weld fillers for mitigation of residual stresses in ferritic and austenitic steel weldscitations
- 2010Neural network modelling of hot deformation of austenite
- 2010Comparison of alloying concepts for Low Transformation Temperature (LTT) welding consumables
- 2010Modelling of residual stress minimization through martensitic transformation in stainless steel welds
- 2009Stainless steel weld metal designed to mitigate residual stressescitations
- 2009Bainite orientation in plastically deformed austenitecitations
- 2008Joining ceramics to metals using metallic foamcitations
Places of action
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article
Mechanical Properties and Processing Techniques of Bulk Metal–Organic Framework Glasses
Abstract
Melt quenched metal–organic framework (MOF) glasses define a new category of glass, distinct from metallic, organic, and inorganic glasses, owing to the dominant role of metal–ligand coordination bonding. The mechanical properties of glasses in general are important given their application in protective coatings and display technologies, though little is known about MOF glasses in this respect. The experimental elucidation of key properties such as their scratch resistance has been limited by the lack of processing methodologies capable of producing bulk glass samples. Here, nanoindentation was used to investigate the Young’s modulus and hardness of four melt-quenched glasses formed from zeolitic imidazolate frameworks (ZIF): a g ZIF-4, a g ZIF-62, a g ZIF-76, and a g ZIF-76-mbIm. The creep resistance of the melt-quenched glasses was studied via strain-rate jump (SRJ) tests and through constant load and hold (CLH) indentation creep experiments. Values for the strain-rate sensitivity were found to be close to those for other glassy polymers and Se-rich GeSe chalcogenide glasses. Vacuum hot-pressing of a g ZIF-62 resulted in an inhomogeneous bulk sample containing the glass and amorphous non-melt-quenched a ZIF-62. Remelting and annealing, however, resulted in the fabrication of a transparent, bubble-free bulk specimen, which allowed the first scratch testing experiments to be performed on an MOF glass.