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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Montini, Tiziano
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (32/32 displayed)
- 2018Metal-free dual-phase full organic carbon nanotubes/g-C 3 N 4 heteroarchitectures for photocatalytic hydrogen productioncitations
- 2018Smart Pd Catalyst with Improved Thermal Stability Supported on High-Surface-Area LaFeO3Prepared by Atomic Layer Depositioncitations
- 2017The water gas shift reaction over Pt–CeO2 nanoparticles confined within mesoporous SBA-16citations
- 2016Solar and visible light photocatalytic enhancement of halloysite nanotubes/g-C3N4 heteroarchitecturescitations
- 2016Synthesis and photocatalytic application of visible-light active β-Fe2O3/g-C3N4 hybrid nanocompositescitations
- 2016H2 production by photocatalytic reforming of oxygenated compounds using TiO2-based materialscitations
- 2016Photocatalytic valorization of ethanol and glycerol over TiO2 polymorphs for sustainable hydrogen productioncitations
- 2015Photocatalytic H2 production by ethanol photodehydrogenation: Effect of anatase/brookite nanocomposites compositioncitations
- 2015Methane Catalytic Combustion over Hierarchical Pd@CeO2/Si-Al2O3: Effect of the Presence of Watercitations
- 2014TiO2-mesoporous silica nanocomposites: Cooperative effect in the photocatalytic degradation of dyes and drugscitations
- 2014TiO2-Mesoporous Silica Nanocomposites: cooperative effect in the photocatalytic degradation of dyes and drugscitations
- 2013H2 production by selective photo-dehydrogenation of ethanol in gas and liquid phase on CuOx/TiO2 nanocompositescitations
- 2012Hydrogen production from ethanol steam reforming on M/CeO2/YSZ (M = Ru, Pd, Ag) nanocompositescitations
- 2012Vertically oriented CuO/ZnO nanorod arrays: from plasma-assisted synthesis to photocatalytic H2 Productioncitations
- 2011Hydrogen production through alcohol steam reforming on Cu/ZnO-based catalystscitations
- 2011Functionalization of Multiwalled Carbon Nanotubes with Cyclic Nitrones for Materials and Composites: Addressing the Role of CNT Sidewall Defectscitations
- 2010Embedded Ru@ZrO2 catalysts for H2 production by ammonia decompositioncitations
- 2010Synthesis of dispersible Pd@CeO2 nanostructures by self-assemblycitations
- 2010Novel embedded Pd@CeO2 catalysts: a way to active and stable catalystscitations
- 2010Effect of the catalyst load on syngas production in SCT-CPO reactorscitations
- 2010Synthesis of Dispersible Pd@CeO2 Core-Shell Nanostructures by Self-Assemblycitations
- 2009Photocatalytic activity of zinc modified Bi2O3citations
- 2009Synthesis, Characterization and Photocatalytic Activity of NiO-Bi2O3 Nanocompositescitations
- 2009Photocatalytic decolourization of dyes on NiO–ZnO nano-compositescitations
- 2008Development of Catalytic Nanoceramic-loaded Fe-Al-Cr Alloy Fiber Media for Exhaust Gas Purificationcitations
- 2008Phase transitions and CO2 adsorption properties of polymeric magnesium formatecitations
- 2008La0.6Sr0.4Co1-yFeyO3-d perovskites: influence of the Co/Fe atomic ratio on properties and catalytic activity towards alcohol steam-reformingcitations
- 2008Surface Phases and Photocatalytic Activity Correlation of Bi2O3/Bi2O4-x Nanocompositecitations
- 2008Design of Rh@Ce0.2Zr0.8O2-Al2O3 nanocomposite for ethanol steam reformingcitations
- 2007Oxidation Enthalpies for Reduction of Ceria Surfacescitations
- 2007Embedded Rh(1wt %)@Al2O3: Effects of high temperature and prolonged aging under methane partial oxidation conditionscitations
- 2007Rh(1%)@CexZr1-xO2-Al2O3 nanocomposites: active and stable catalysts for Ethanol Steam Reformingcitations
Places of action
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article
Synthesis of Dispersible Pd@CeO2 Core-Shell Nanostructures by Self-Assembly
Abstract
A methodology is described for the preparation of Pd@CeO(2) core-shell nanostructures that are easily dispersible in common organic solvents. The method involves the synthesis of Pd nanoparticles protected by a monolayer of 11-mercaptoundecanoic acid (MUA). The carboxylic groups on the nanoparticle surfaces are used to direct the self-assembly of a cerium(IV) alkoxide around the metal particles, followed by the controlled hydrolysis to form CeO(2). The characterization of the nanostructures by means of different techniques, in particular by electron microscopy, allowed us to demonstrate the nature of core-shell systems, with CeO(2) nanocrystals forming a shell around the MUA-protected Pd core. Finally, an example of the use of these nanostructures as flexible precursors for the preparation of heterogeneous catalysts is reported by investigating the reactivity of Pd@CeO(2)/Al(2)O(3) nanocomposites toward CO oxidation, water-gas shift (WGS), and methanol steam reforming reactions. Together with CO adsorption data, these observations suggest the accessibility of the Pd phase in the nanocomposites.