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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Pan, Jinshan
KTH Royal Institute of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (37/37 displayed)
- 2025Unveiling nano-scale chemical inhomogeneity in surface oxide films formed on V- and N-containing martensite stainless steel by synchrotron X-ray photoelectron emission spectroscopy/microscopy and microscopic X-ray absorption spectroscopycitations
- 2024Unveiling nano-scale chemical inhomogeneity in surface oxide films formed on V- and N-containing martensite stainless steel by synchrotron X-ray photoelectron emission spectroscopy/microscopy and microscopic X-ray absorption spectroscopycitations
- 2024Dynamics of early-stage oxide formation on a Ni-Cr-Mo alloycitations
- 2023Penetration of corrosive species into copper exposed to simulated O2-free groundwater by time-of-flight secondary ion mass spectrometry (ToF-SIMS)citations
- 2023Understanding passive film degradation and its effect on hydrogen embrittlement of super duplex stainless steel-Synchrotron X-ray and electrochemical measurements combined with CalPhaD and ab-initio computational studiescitations
- 2023In situ quantitative analysis of electrochemical oxide film development on metal surfaces using ambient pressure X-ray photoelectron spectroscopy : Industrial alloyscitations
- 2023The causation of hydrogen embrittlement of duplex stainless steel : Phase instability of the austenite phase and ductile-to-brittle transition of the ferrite phase – Synergy between experiments and modellingcitations
- 2023The Causation of Hydrogen Embrittlement of Duplex Stainless Steel: Phase Instability of the Austenite Phase and Ductile-to-Brittle Transition of the Ferrite Phase – Synergy between Experiments and Modellingcitations
- 2023Understanding Passive Film Degradation and its Effect on Hydrogen Embrittlement of Super Duplex Stainless Steel – Synchrotron X-ray and Electrochemical Measurements combined with CalPhaD and ab-initio Computational Studiescitations
- 2023Synchrotron XPS and Electrochemical Study of Aging Effect on Passive Film of Ni Alloyscitations
- 2023Reply to comment on “Penetration of corrosive species into copper exposed to simulated O 2 -free groundwater by time-of-flight secondary ion mass spectrometry (ToF-SIMS)”citations
- 2022Thickness and composition of native oxides and near-surface regions of Ni superalloyscitations
- 2022Thickness and composition of native oxides and near-surface regions of Ni superalloyscitations
- 2022Hydrogen-Induced Micro-Strain Evolution in Super Duplex Stainless Steel—Correlative High-Energy X-Ray Diffraction, Electron Backscattered Diffraction, and Digital Image Correlationcitations
- 2021Corrosion of copper in sulphide containing environment: the role and properties of sulphide films – Annual report 2020
- 2021Corrosion-induced microstructure degradation of copper in sulfide-containing simulated anoxic groundwater studied by synchrotron high-energy X-ray diffraction and ab-initio density functional theory calculationcitations
- 2020Lateral Variation of the Native Passive Film on Super Duplex Stainless Steel Resolved by Synchrotron Hard X-Ray Photoelectron Emission Microscopycitations
- 2020Metastable Precursor Structures in Hydrogen-infused Super Duplex Stainless Steel Microstructure – An Operando Diffraction Experimentcitations
- 2020Operando time- and space-resolved high-energy X-ray diffraction measurement to understand hydrogen-microstructure interactions in duplex stainless steelcitations
- 2020Time-resolved Grazing-Incidence X-ray Diffraction Measurement to Understand the Effect of Hydrogen on Surface Strain Development in Super Duplex Stainless Steelcitations
- 2019Influence of Surface Strain on Passive Film Formation of Duplex Stainless Steel and Its Degradation in Corrosive Environmentcitations
- 2019Redefining passivity breakdown of super duplex stainless steel by electrochemical operando synchrotron near surface X-ray analysescitations
- 2019Characterization of native oxide and passive film on austenite/ferrite phases of duplex stainless steel using synchrotron haxpeemcitations
- 2019Passive film characterisation of duplex stainless steel using scanning Kelvin probe force microscopy in combination with electrochemical measurementscitations
- 2018Hydrogen Embrittlement of Super Duplex Stainless Steel – Towards Understanding the Effects of Microstructure and Straincitations
- 2018Corrosion Inhibition of Aluminum Alloy AA6063-T5 by Vanadates: Microstructure Characterization and Corrosion Analysiscitations
- 2017Integration of electrochemical and synchrotron-based X-ray techniques for in-situ investigation of aluminum anodizationcitations
- 2015Long-term corrosion protection by a thin nano-composite coatingcitations
- 2014Direct measurement of colloidal interactions between polyaniline surfaces in a uv-curable coating formulation:the effect of surface hydrophilicity/ hydrophobicity and resin compositioncitations
- 2014Study of Corrosion Behavior of a 2507 Super Duplex Stainless Steel : Influence of Quenched-in and Isothermal Nitrides
- 2014Direct measurement of colloidal interactions between polyaniline surfaces in a uv-curable coating formulationcitations
- 2014Role of microstructure on corrosion initiation of an experimental tool alloy : A Quantitative Nanomechanical Property Mapping studycitations
- 2013Study of corrosion behavior of a 22% Cr duplex stainless steel : influence of nano-sized chromium nitrides and exposure temperaturecitations
- 2013The effect of superhydrophobic wetting state on corrosion protection - The AKD examplecitations
- 2013Tribological Properties Mapping: Local Variation in Friction Coefficient and Adhesioncitations
- 2012Engineering of bone fixation metal implants biointerface : application of parylene C as versatile protective coatingcitations
- 2011Toward Homogeneous Nanostructured Polyaniline/Resin Blendscitations
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article
Toward Homogeneous Nanostructured Polyaniline/Resin Blends
Abstract
The high interest in applications of conducting polymers, especially polyaniline (PANI), makes it important to overcome limitations for effective usage due to poor processability and solubility. One promising approach is to make blends of PANI in polymeric resins. However, in this approach other problems related to the difficulty of achieving a homogeneous PANI dispersion arise. The present article is focused on this general problem, and we discuss how the synthesis method, choice of dopant and solvent as well as interfacial energies influence the dispersibility. For this purpose, different synthesis methods and dopants have been employed to prepare nanostructures of polyaniline. Dynamic light scattering analysis of dispersions of the synthesized particles in several solvents was employed in order to understand how the choice of solvent affects PANI aggregation. Further information on this subject was achieved by scanning electron microscopy studies of PANI powders dried from various solutions. On the basis of these results, acetone was found to be a suitable dispersion medium for PANI. The polymer matrix used to make the blends in this work is a UV-curing solvent-free resin. Therefore, there is no low molecular weight liquid in the system to facilitate the mixing process and promote formation of homogeneous dispersions. Thus, a good compatibility of the components becomes crucial. For this reason, surface tension and contact angle measurements were utilized for characterizing the surface energy of the PANI particles and the polyester acrylate (PEA) resin, and also for calculating the interfacial energy between these two components that revealed good compatibility within the PANI/PEA blend. A novel technique, based on centrifugal sedimentation analysis, was employed in order to determine the PANI particle size in PEA resin, and high dispersion stability of the PANI/PEA blends was suggested by evaluation of the sedimentation data.