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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Crespi, Stefano
University of Groningen
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024All-visible-light-driven stiff-stilbene photoswitchescitations
- 2023Designing P-type bi-stable overcrowded alkene-based chiroptical photoswitchescitations
- 2022Controlling forward and backward rotary molecular motion on demandcitations
- 2022Controlling forward and backward rotary molecular motion on demandcitations
- 2022Cooperative light-induced breathing of soft porous crystals via azobenzene bucklingcitations
- 2019Substituent Effects on 3-Arylazoindole Photoswitchescitations
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article
Substituent Effects on 3-Arylazoindole Photoswitches
Abstract
The development and investigation of heteroazo switches has flourished in recent years. Because of their specific photophysical and photochemical properties, they find versatile applications from material science to medicine. However, a deep mechanistic understanding is needed to be able to predict the properties of such azoswitches. In particular, the effect of different substituents on the azo chromophore is of great interest as they are often crucial for embedding the molecular switch into a system of interest. Herein, we provide a detailed spectroscopic and computational study on the influence of substituents on 3-phenylazoindoles chosen as models. We will point out changes in absorption properties and analyze the photostationary state of the thermally labile Z isomers through computational means to provide a general structure-property relationship guideline for further use of these compounds.