| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Smetana, Volodymyr
Stockholm University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (55/55 displayed)
- 2024La-Ni-Si:A Gold Mine with a Diamond
- 2024Unusual superconductivity in crystallographically disordered RT2−xSn2 compounds
- 2024The crystal and electronic structure of RE$_{23}$Co$_{6.7}$In$_{20.3}$ (RE = Gd–Tm, Lu) : a new structure type based on intergrowth of AlB$_{2}$- and CsCl-type related slabscitations
- 2024The crystal and electronic structure of RE23Co6.7In20.3 (RE = Gd–Tm, Lu)citations
- 2024La-Ni-Si : a gold mine with a diamond
- 2024Intermetallics of 4:4:1 and 3:3:1 series in La–(Co,Ni)–M (M = Bi, Pb, Te, Sb, Sn and Ga, Al) systems and their propertiescitations
- 2024Unusual superconductivity in crystallographically disordered RT 2−x Sn 2 compounds
- 2024Ternary gallide Zr 7 Pd 7–x Ga 3+x (0 ≤ x ≤ 1.8):Synthesis, crystal and electronic structurescitations
- 2024La-Ni-Si: A Gold Mine with a Diamond
- 2023The Prolific Ternary System Pt/Sn/Ndcitations
- 2023Solubility limits, magnetic and magnetocaloric properties of MoB-type GdCo x Ni 1−x (0.47 ≤ x ≤ 0.72)citations
- 2023Investigation of the role of hydrogen bonding in ionic liquid-like salts with both N- and S-soft donorscitations
- 2023Crystal and electronic structures of the new ternary gallide Zr12Pd40−xGa31+y (x = 0–1.5, y = 0–0.5)citations
- 2023Enhanced stability and complex phase behaviour of organic-inorganic green-emitting ionic manganese halidescitations
- 2023Crystal and electronic structures of the new ternary gallide Zr 12 Pd 40−x Ga 31+y (x = 0–1.5, y = 0–0.5)citations
- 2023The Prolific Ternary System Pt/Sn/Nd:Insertion of Pt into the Structures of Sn/Nd Intermetallics Yields Structural Complexity and Wealthcitations
- 2023Honeycomb Constructs in the La-Ni Intermetallics : Controlling Dimensionality via p-Element Substitutioncitations
- 2022Four ternary silicides in the La-Ni-Si system:from polyanionic layers to frameworkscitations
- 2022Four ternary silicides in the La-Ni-Si system : from polyanionic layers to frameworkscitations
- 2022Crystal and electronic structures of a new hexagonal silicide Sc 38 Co 144 Si 97
- 2022Crystal and electronic structures of a new hexagonal silicide Sc38Co144Si97
- 2022Four ternary silicides in the La-Ni-Si systemcitations
- 2021New intermetallics R1+xZr1−xNi (R = Er–Tm, x ~ 0.5) with the TiNiSi type of structurecitations
- 2021Crystal and Magnetic Structures of the Ternary Ho2Ni0.8Si1.2and Ho2Ni0.8Ge1.2 Compoundscitations
- 2021Crystal and Magnetic Structures of the Ternary Ho2Ni0.8Si1.2 and Ho2Ni0.8Ge1.2 Compounds: An Example of Intermetallics Crystallizing with the Zr2Ni1{textendash}{xP} Prototypecitations
- 2020Metallic alloys at the edge of complexitycitations
- 2020A fivefold UO22+ node is a path to dodecagonal quasicrystal approximants in coordination polymerscitations
- 2020Binary Intermetallics in the 70 atom % R Region of Two R-Pd Systems (R = Tb and Er)citations
- 2020Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La-Sm)citations
- 2020Fluorinated Cationic Iridium(III) Complex Yielding an Exceptional, Efficient, and Long-Lived Red-Light-Emitting Electrochemical Cellcitations
- 2020Forcing Dicyanamide Coordination to f-Elements by Dissolution in Dicyanamide-Based Ionic Liquidscitations
- 2020Dehydration of UO2Cl2·3H2O and Nd(NO3)3·6H2O with a Soft Donor Ligand and Comparison of Their Interactions through X-ray Diffraction and Theoretical Investigationcitations
- 2019Alternative to the Popular Imidazolium Ionic Liquidscitations
- 2019Ionothermal Synthesis, Structures, and Magnetism of Three New Open Framework Iron Halide-Phosphatescitations
- 2018Supramolecularly Caged Green-Emitting Ionic Ir(III)-Based Complex with Fluorinated C^N Ligands and Its Application in Light-Emitting Electrochemical Cellscitations
- 2018R14(Au, M)51 (R = Y, La-Nd, Sm-Tb, Ho, Er, Yb, Lu; M = Al, Ga, Ge, In, Sn, Sb, Bi)citations
- 2018Controlling magnetism via transition metal exchange in the series of intermetallics Eu(T1, T2)5In (T = Cu, Ag, Au)citations
- 2018R14(Au, M)51(R = Y, La-Nd, Sm-Tb, Ho, Er, Yb, Lu; M = Al, Ga, Ge, In, Sn, Sb, Bi): Stability Ranges and Site Preference in the Gd14Ag51Structure Typecitations
- 2018Bringing order to large-scale disordered complex metal alloyscitations
- 2018From the Nonexistent Polar Intermetallic Pt3Pr4 via Pt2- xPr3 to Pt/Sn/Pr Ternariescitations
- 2018An Obscured or Nonexistent Binary Intermetallic, CO7Pr17, Its Existent Neighbor Co2Pr5, and Two New Ternaries in the System Co/Sn/Pr, CoSn3Pr1−x, and Co2−xSn7Pr3citations
- 2017Layered Structures and Disordered Polyanionic Nets in the Cation-Poor Polar Intermetallics CsAu1.4Ga2.8 and CsAu2Ga2.6citations
- 2017Gold Polar Intermetallicscitations
- 2017R3Au9Pn (R = Y, Gd-Tm; Pn = Sb, Bi): A Link between Cu10Sn3 and Gd14Ag51citations
- 2017R3Au9Pn (R = Y, Gd-Tm; Pn = Sb, Bi)citations
- 2016New R3Pd5 Compounds (R = Sc, Y, Gd-Lu)citations
- 2016New R3Pd5Compounds (R = Sc, Y, Gd–Lu): Formation and Stability, Crystal Structure, and Antiferromagnetismcitations
- 2016Gold in the Layered Structures of R3Au7Sn3: From Relativity to Versatilitycitations
- 2016Gd3Ni2 and Gd3CoxNi2-xcitations
- 2016Gd3Ni2and Gd3CoxNi2−x: magnetism and unexpected Co/Ni crystallographic orderingcitations
- 2016Gold in the Layered Structures of R3Au7Sn3citations
- 2015Cation-Poor Complex Metallic Alloys in Ba(Eu)-Au-Al(Ga) Systemscitations
- 2015Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+ xGa3- x (Ae = Ba and Eu)citations
- 2015Gold-rich R3Au7Sn3: establishing the interdependence between electronic features and physical propertiescitations
- 2015Gold-rich R3Au7Sn3citations
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article
From the Nonexistent Polar Intermetallic Pt3Pr4 via Pt2- xPr3 to Pt/Sn/Pr Ternaries
Abstract
<p>Although the Pt-Pr phase diagram has been explored well, recent work on rare-earth metal cluster halides with endohedral transition metal atoms has provided a new binary intermetallic that is nonexistent in the known phase diagram: The binary Pt<sub>3</sub>Pr<sub>4</sub> (1) crystallizes in a new structure type (mP56, P2<sub>1</sub>/c, a = 12.353(2) Å, b = 7.4837(9) Å, c = 17.279(2) Å, β = 118.003(7)°, Z = 8) with six crystallographically independent Pt as well as eight Pr positions. The subsequent detailed investigation has led to another previously unreported, binary phase with the Ga<sub>2</sub>Gd<sub>3</sub> structure type, Pt<sub>2-x</sub>Pr<sub>3</sub> (2, tI80, I4/mcm, a = 11.931(9) Å, c = 14.45(1) Å, Z = 16), that is practically overlapping with the rhombohedral Pt<sub>2</sub>Pr<sub>3</sub> existing in the phase diagram. Application of different tin containing fluxes to reproduce the newly detected phases brought about two almost iso-compositional ternary compounds with Sn, Pt<sub>4</sub>Sn<sub>6</sub>Pr<sub>2.91</sub> (3), and Pt<sub>4</sub>Sn<sub>6</sub>Pr<sub>3</sub> (4), as well as Pt<sub>12</sub>Sn<sub>24</sub>Pr<sub>4.84</sub> (5). 3 is a representative of the Pt<sub>4</sub>Ge<sub>6</sub>Ce<sub>3</sub> type (oP52, Pnma, a = 7.2863(3) Å, b = 4.4909(2) Å, c = 35.114(2) Å), while 4 represents a new variant of the prolific T<sub>4</sub>E<sub>6</sub>R<sub>3</sub> family (T = transition metal, E = main group (semi)metal, R = rare-earth metal; Pt<sub>4</sub>Sn<sub>6</sub>Pr<sub>3</sub>: oP52, Pnma, a = 27.623(1) Å, b = 4.5958(2) Å, c = 9.3499(5) Å). Pt<sub>12</sub>Sn<sub>24</sub>Pr<sub>5-x</sub> (5) crystallizes as a variant of the Ni<sub>8</sub>Sn<sub>16</sub>Gd<sub>3</sub> type (cI82, Im3?, a = 12.274(1) Å, Z = 2). Electronic structure calculations provide hints on the origin of the structural changes (pseudo-polymorphism) for Pt<sub>x</sub>Pr<sub>3</sub> with x = 1.97 and 2.00, respectively, and reveal that heteroatomic Pt-Pr bonding strongly dominates in both binaries while the addition of the reactive metal tin leads to dominating Pt-Sn bonding interactions in the ternaries; Pt-Pt bonding interactions are strong but represent a minority in the binaries and are not present at all in the ternaries.</p>