| People | Locations | Statistics |
|---|---|---|
| Naji, M. |
| |
| Motta, Antonella |
| |
| Aletan, Dirar |
| |
| Mohamed, Tarek |
| |
| Ertürk, Emre |
| |
| Taccardi, Nicola |
| |
| Kononenko, Denys |
| |
| Petrov, R. H. | Madrid |
|
| Alshaaer, Mazen | Brussels |
|
| Bih, L. |
| |
| Casati, R. |
| |
| Muller, Hermance |
| |
| Kočí, Jan | Prague |
|
| Šuljagić, Marija |
| |
| Kalteremidou, Kalliopi-Artemi | Brussels |
|
| Azam, Siraj |
| |
| Ospanova, Alyiya |
| |
| Blanpain, Bart |
| |
| Ali, M. A. |
| |
| Popa, V. |
| |
| Rančić, M. |
| |
| Ollier, Nadège |
| |
| Azevedo, Nuno Monteiro |
| |
| Landes, Michael |
| |
| Rignanese, Gian-Marco |
|
Smetana, Volodymyr
Stockholm University
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (55/55 displayed)
- 2024La-Ni-Si:A Gold Mine with a Diamond
- 2024Unusual superconductivity in crystallographically disordered RT2−xSn2 compounds
- 2024The crystal and electronic structure of RE$_{23}$Co$_{6.7}$In$_{20.3}$ (RE = Gd–Tm, Lu) : a new structure type based on intergrowth of AlB$_{2}$- and CsCl-type related slabscitations
- 2024The crystal and electronic structure of RE23Co6.7In20.3 (RE = Gd–Tm, Lu)citations
- 2024La-Ni-Si : a gold mine with a diamond
- 2024Intermetallics of 4:4:1 and 3:3:1 series in La–(Co,Ni)–M (M = Bi, Pb, Te, Sb, Sn and Ga, Al) systems and their propertiescitations
- 2024Unusual superconductivity in crystallographically disordered RT 2−x Sn 2 compounds
- 2024Ternary gallide Zr 7 Pd 7–x Ga 3+x (0 ≤ x ≤ 1.8):Synthesis, crystal and electronic structurescitations
- 2024La-Ni-Si: A Gold Mine with a Diamond
- 2023The Prolific Ternary System Pt/Sn/Ndcitations
- 2023Solubility limits, magnetic and magnetocaloric properties of MoB-type GdCo x Ni 1−x (0.47 ≤ x ≤ 0.72)citations
- 2023Investigation of the role of hydrogen bonding in ionic liquid-like salts with both N- and S-soft donorscitations
- 2023Crystal and electronic structures of the new ternary gallide Zr12Pd40−xGa31+y (x = 0–1.5, y = 0–0.5)citations
- 2023Enhanced stability and complex phase behaviour of organic-inorganic green-emitting ionic manganese halidescitations
- 2023Crystal and electronic structures of the new ternary gallide Zr 12 Pd 40−x Ga 31+y (x = 0–1.5, y = 0–0.5)citations
- 2023The Prolific Ternary System Pt/Sn/Nd:Insertion of Pt into the Structures of Sn/Nd Intermetallics Yields Structural Complexity and Wealthcitations
- 2023Honeycomb Constructs in the La-Ni Intermetallics : Controlling Dimensionality via p-Element Substitutioncitations
- 2022Four ternary silicides in the La-Ni-Si system:from polyanionic layers to frameworkscitations
- 2022Four ternary silicides in the La-Ni-Si system : from polyanionic layers to frameworkscitations
- 2022Crystal and electronic structures of a new hexagonal silicide Sc 38 Co 144 Si 97
- 2022Crystal and electronic structures of a new hexagonal silicide Sc38Co144Si97
- 2022Four ternary silicides in the La-Ni-Si systemcitations
- 2021New intermetallics R1+xZr1−xNi (R = Er–Tm, x ~ 0.5) with the TiNiSi type of structurecitations
- 2021Crystal and Magnetic Structures of the Ternary Ho2Ni0.8Si1.2and Ho2Ni0.8Ge1.2 Compoundscitations
- 2021Crystal and Magnetic Structures of the Ternary Ho2Ni0.8Si1.2 and Ho2Ni0.8Ge1.2 Compounds: An Example of Intermetallics Crystallizing with the Zr2Ni1{textendash}{xP} Prototypecitations
- 2020Metallic alloys at the edge of complexitycitations
- 2020A fivefold UO22+ node is a path to dodecagonal quasicrystal approximants in coordination polymerscitations
- 2020Binary Intermetallics in the 70 atom % R Region of Two R-Pd Systems (R = Tb and Er)citations
- 2020Ternary Polar Intermetallics within the Pt/Sn/R Systems (R = La-Sm)citations
- 2020Fluorinated Cationic Iridium(III) Complex Yielding an Exceptional, Efficient, and Long-Lived Red-Light-Emitting Electrochemical Cellcitations
- 2020Forcing Dicyanamide Coordination to f-Elements by Dissolution in Dicyanamide-Based Ionic Liquidscitations
- 2020Dehydration of UO2Cl2·3H2O and Nd(NO3)3·6H2O with a Soft Donor Ligand and Comparison of Their Interactions through X-ray Diffraction and Theoretical Investigationcitations
- 2019Alternative to the Popular Imidazolium Ionic Liquidscitations
- 2019Ionothermal Synthesis, Structures, and Magnetism of Three New Open Framework Iron Halide-Phosphatescitations
- 2018Supramolecularly Caged Green-Emitting Ionic Ir(III)-Based Complex with Fluorinated C^N Ligands and Its Application in Light-Emitting Electrochemical Cellscitations
- 2018R14(Au, M)51 (R = Y, La-Nd, Sm-Tb, Ho, Er, Yb, Lu; M = Al, Ga, Ge, In, Sn, Sb, Bi)citations
- 2018Controlling magnetism via transition metal exchange in the series of intermetallics Eu(T1, T2)5In (T = Cu, Ag, Au)citations
- 2018R14(Au, M)51(R = Y, La-Nd, Sm-Tb, Ho, Er, Yb, Lu; M = Al, Ga, Ge, In, Sn, Sb, Bi): Stability Ranges and Site Preference in the Gd14Ag51Structure Typecitations
- 2018Bringing order to large-scale disordered complex metal alloyscitations
- 2018From the Nonexistent Polar Intermetallic Pt3Pr4 via Pt2- xPr3 to Pt/Sn/Pr Ternariescitations
- 2018An Obscured or Nonexistent Binary Intermetallic, CO7Pr17, Its Existent Neighbor Co2Pr5, and Two New Ternaries in the System Co/Sn/Pr, CoSn3Pr1−x, and Co2−xSn7Pr3citations
- 2017Layered Structures and Disordered Polyanionic Nets in the Cation-Poor Polar Intermetallics CsAu1.4Ga2.8 and CsAu2Ga2.6citations
- 2017Gold Polar Intermetallicscitations
- 2017R3Au9Pn (R = Y, Gd-Tm; Pn = Sb, Bi): A Link between Cu10Sn3 and Gd14Ag51citations
- 2017R3Au9Pn (R = Y, Gd-Tm; Pn = Sb, Bi)citations
- 2016New R3Pd5 Compounds (R = Sc, Y, Gd-Lu)citations
- 2016New R3Pd5Compounds (R = Sc, Y, Gd–Lu): Formation and Stability, Crystal Structure, and Antiferromagnetismcitations
- 2016Gold in the Layered Structures of R3Au7Sn3: From Relativity to Versatilitycitations
- 2016Gd3Ni2 and Gd3CoxNi2-xcitations
- 2016Gd3Ni2and Gd3CoxNi2−x: magnetism and unexpected Co/Ni crystallographic orderingcitations
- 2016Gold in the Layered Structures of R3Au7Sn3citations
- 2015Cation-Poor Complex Metallic Alloys in Ba(Eu)-Au-Al(Ga) Systemscitations
- 2015Crystal Structure and Bonding in BaAu5Ga2 and AeAu4+ xGa3- x (Ae = Ba and Eu)citations
- 2015Gold-rich R3Au7Sn3: establishing the interdependence between electronic features and physical propertiescitations
- 2015Gold-rich R3Au7Sn3citations
Places of action
| Organizations | Location | People |
|---|
article
R3Au9Pn (R = Y, Gd-Tm; Pn = Sb, Bi)
Abstract
<p>A new series of intermetallic compounds R<sub>3</sub>Au<sub>9</sub>Pn (R = Y, Gd-Tm; Pn = Sb, Bi) has been discovered during the explorations of the Au-rich parts of rare-earth-containing ternary systems with p-block elements. The existence of the series is strongly restricted by both geometric and electronic factors. R<sub>3</sub>Au<sub>9</sub>Pn compounds crystallize in the hexagonal crystal system with space group P6<sub>3</sub>/m (a = 8.08-8.24 Å, c = 8.98-9.08 Å). All compounds feature Au-Pn, formally anionic, networks built up by layers of alternating edge-sharing Au@Au<sub>6</sub> and Sb@Au<sub>6</sub> trigonal antiprisms of overall composition Au<sub>6/2</sub>Pn connected through additional Au atoms and separated by a triangular cationic substructure formed by R atoms. From a first look, the series appears to be isostructural with recently reported R<sub>3</sub>Au<sub>7</sub>Sn<sub>3</sub> (a ternary ordered derivative of the Cu<sub>10</sub>Sn<sub>3</sub>-structure type), but no example of R<sub>3</sub>Au<sub>9</sub>M is known when M is a triel or tetrel element. R<sub>3</sub>Au<sub>9</sub>Pn also contains Au@Au<sub>6</sub>Au<sub>2</sub>R<sub>3</sub> fully capped trigonal prisms, which are found to be isostructural with those found in the well-researched R<sub>14</sub>Au<sub>51</sub> series. This structural motif, not present in R<sub>3</sub>Au<sub>7</sub>Sn<sub>3</sub>, represents a previously unrecognized link between Cu<sub>10</sub>Sn<sub>3</sub> and Gd<sub>14</sub>Ag<sub>51</sub> parent structure types. Magnetic property measurements carried out for Ho<sub>3</sub>Au<sub>9</sub>Sb reveal a complex magnetic structure characterized by antiferromagnetic interactions at low temperature (T<sub>N</sub> = 10 K). Two metamagnetic transitions occur at high field with a change from antiferromagnetic toward ferromagnetic ordering. Density functional theory based computations were performed to understand the materials' properties and to shed some light on the stability ranges. This allowed a better understanding of the bonding pattern, especially of the Au-containing substructure, and elucidation of the role of the third element in the stability of the structure type.</p>