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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Grönroos, Antti
VTT Technical Research Centre of Finland
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2022Pilot-scale modification of polyethersulfone membrane with a size and charge selective nanocellulose layercitations
- 2021Membrane-based conceptual design of reuse water production from candy factory wastewatercitations
- 2010Ultrasonically Enhanced Disintegration. Polymers, Sludge, and Contaminated Soil
- 2009New processing technique for viscous amorphous materials and characterisation of their stickiness and deformabilitycitations
- 2004Ultrasonic depolymerization of aqueous carboxymethylcellulosecitations
- 2001Research for efficient separation
- 2001Ultrasonic depolymerization of aqueous polyvinyl alcoholcitations
Places of action
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article
Ultrasonic depolymerization of aqueous carboxymethylcellulose
Abstract
Prolonged exposure of solutions of macromolecules to high-energy ultrasonic waves produces a permanent reduction in viscosity. However, the exact mechanism by which degradation occurs is still open to discussion. According to this study hydrodynamic forces played the primary role in degradation process. This study showed that there is an optimal carboxymethylcellulose (CMC) concentration to the most efficient degradation. Ultrasound degraded preferentially large CMC molecules and cleavage took place roughly at the centre of the CMC molecules. Degradation of CMC did not proceed below a certain molecular mass. During ultrasonic degradation the molecular mass distribution narrowed. For any polymer degradation process to become acceptable to industry, it is important to be able to specify the sonication conditions to produce a particular relative molecular mass distribution.