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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Dendisova, Marcela
University of Chemistry and Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (6/6 displayed)
- 2024Characterization of Modified PVDF Membranes Using Fourier Transform Infrared and Raman Microscopy and Infrared Nanoimaging: Challenges and Advantages of Individual Methodscitations
- 2023Flexible, ultrathin and light films from one-dimensional nanostructures of polypyrrole and cellulose nanofibers for high performance electromagnetic interference shieldingcitations
- 2022Tailor-made dual doping for morphology control of polyaniline chains in cellulose nanofiber-based flexible electrodes: electrical and electrochemical performancecitations
- 2021Elaboration and properties of nanofibrillated cellulose composites with polypyrrole nanotubes or their carbonized analogscitations
- 2021Immobilization of green-synthesized silver nanoparticles for micro- and nano-spectroscopic applications: What is the role of used short amino- and thio-linkers and immobilization procedure on the SERS spectra?citations
- 2020New approach for the development of reduced graphene oxide/polyaniline nanocomposites via sacrificial surfactant-stabilized reduced graphene oxidecitations
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article
Elaboration and properties of nanofibrillated cellulose composites with polypyrrole nanotubes or their carbonized analogs
Abstract
Flexible electrically conductive composites based on renewable resources have attracted a growing interest for the development of high performance sustainable electronic and energy storage devices. In this study, electrically conductive flexible composite films based on nanofibrillated cellulose (NFC) and conductive nanotubular fillers were elaborated using environmentally friendly approach. Three conductive fillers were tested, specifically polypyrrole nanotubes (PPy-NT), carbonized polypyrrole nanotubes (C-PPy-NT) and commercially available multi-walled carbon nanotubes (MWCNT) for comparison. The prepared films were assessed for potential applications as electrodes for energy storage devices or protective shields for electromagnetic interference (EMI) shielding in the microwave region. Electrical conductivity measurement revealed that NFC films loaded with PPy-NT (PPy-NT/NFC) exhibited the highest conductivity (1.16 S cm–1) compared to those loaded with C-PPy-NT or MWCNT. PPy-NT/NFC displayed the highest gravimetric capacitance among all tested films reaching 209.7 F g−1 at 10 mV s−1 in a stable potential window (from –0.5 to 0.15 V vs. MSE). When larger potential window (from –0.5 to 0.5 V vs. MSE) was applied, PPy-NT/NFC exhibited fast capacitance decay (to 80% of initial value in 50 cycles). The promising properties of PPy-NT/NFC electrode material were further confirmed in full-cell measurements in symmetric arrangement providing stable performance and 74 F g−1. Meanwhile, C-PPy-NT/NFC and MWCNT/NFC displayed significantly lower capacitances (below 20 F g−1 at 10 mV s−1) but better cycling stability in a larger potential window. The highest shielding efficiency of all NFC-based composites was observed in case of PPy-NT/NFC, reaching 75% in the C-band region. © 2021 Elsevier B.V.