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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cassagnau, Philippe
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (62/62 displayed)
- 2023Synthesis, Recycling and High‐Throughput Reprocessing of Phase‐Separated Vitrimer‐Thermoplastic Blendscitations
- 2022In situ coupled mechanical/electrical/WAXS/SAXS investigations on ethylene propylene diene monomer resin/carbon black nanocompositescitations
- 2022New Reactive Formulations For Polypropylene Foamscitations
- 2021Viscoelastic behaviour of highly filled polypropylene with solid and liquid Tin microparticles: influence of the stearic acid additivecitations
- 2020Impact of Polymer Binders on the Structure of Highly Filled Zirconia Feedstockscitations
- 2018A model for the electrical conductivity variation of molten polymer filled with carbon nanotubes under extensional deformationcitations
- 2018Specific properties of in situ ruthenium-catalyzed polyamide 12/polydimethylsiloxane compatibilized blendcitations
- 2018Conductive elastomer composites with low percolation threshold based on carbon black and epoxidized natural rubbercitations
- 2017Effect of phosphorous-modified silica on the flame retardancy of polybutylene terephthalate based nanocompositescitations
- 2017In situ Synthesis of Inorganic and/or Organic Phases in Thermoplastic Polymers by Reactive Extrusioncitations
- 2016Structuring of non-Brownian ferrite particles in molten polypropylene: Viscoelastic analysiscitations
- 2016Elaboration of low viscosity and high impact polypropylene blends through reactive extrusioncitations
- 2015CO2 nano-foaming of nanostructured PMMAcitations
- 2015Flexible 0-3 Ceramic-Polymer Composites of Barium Titanate and Epoxidized Natural Rubbercitations
- 2015Polymer nano-foams for insulating applications prepared from CO2 foamingcitations
- 2015Influence of organophosphorous silica precursor on the thermal and fire behaviour of a PA66/PA6 copolymercitations
- 2015Synthesis of a new organophosphorous alkoxysilane precursor and its effect on the thermal and fire behavior of a PA66/PA6 copolymercitations
- 2015Effect of phosphorous-modified silica on the flame retardancy of polypropylene based nanocompositescitations
- 2014High shear processing of (PP/EPR)/Silica nanocomposites: Improvement of morphology and propertiescitations
- 2014Structuration, selective dispersion and compatibilizing effect of (nano)fillers in polymer blends ; Structuration, selective dispersion and compatibilizing effect of (nano)fillers in polymer blends: reviewcitations
- 2014Viscoelasticity and dynamics of suspensions and nanocomposites filled with nanaprrticles of different aspect ratios
- 2014Residence time distribution in a high shear twin screw extrudercitations
- 2014Contribution of High-shear Processing to the Compatibilization of (PP/EPR)/PE Ternary Blends
- 2013Linear viscoelasticity and dynamics of suspensions and molten polymers filled with nanoparticles of different aspect ratioscitations
- 2013Effect of barium titanate in thermoplastic elastomer based on poly(vinylidene fluoride) and epoxidized natural rubber blends
- 2013Phosphorylated silica/polyamide 6 nanocomposites synthesis by in situ sol-gel method in molten conditions: Impact on the fire-retardancycitations
- 2013Viscosity and dynamics of nanorod (carbon nanotubes, cellulose whiskers, stiff polymers and polymer fibers) suspensionscitations
- 2013Dynamic behavior of crosslinked amphiphilic block copolymer nanofibers dispersed in liquid poly(ethylene oxide) below and above their glass transition temperaturecitations
- 2013New Polymer Materials for Steel/Polymer/Steel Laminates in Automotive Applicationscitations
- 2013Co-Continuous Phase Structure and Properties of Poly(vinylidene Fluoride)/Epoxidized Natural Rubber Blendscitations
- 2012Physicochemical properties of organoclay filled polylactic acid/natural rubber blend bionanocompositescitations
- 2012Sol-gel reactions of silicon alkoxides as a tool for design nanocomposites based on a biopolymer (PLA)
- 2011New polymer/steel solution for automotive applicationscitations
- 2011Influence of a non-polar medium (alkane and molten polypropylene) on the titanium n-butoxide hydrolysis-condensation reactionscitations
- 2011Reactive compatibilization of PA12/plasticized starch blends: Towards improved mechanical propertiescitations
- 2011Reactive extrusion processing of polypropylene/TiO2 nanocomposites by in situ synthesis of the nanofillers: Experiments and modelingcitations
- 2010Current issues in research on structure-property relationships in polymer nanocomposites
- 2010Bio-Sourced networks from thermal polyaddition of a starch-derived α-azide-ω-alkyne AB monomer with an A2B2 aliphatic cross-linker
- 2010Morphology and Viscoelasticity of PP/TiO2 Nanocomposites Prepared by In Situ Sol-Gel Methodcitations
- 2010Bio-Sourced Networks from Thermal Polyaddition of a Starch-Derived alpha-Azide-omega-Alkyne AB Monomer with an A(2)B(2) Aliphatic Cross-linker
- 2010In situ polymerization of L-Lactide in the presence of fumed silicacitations
- 2010Rheological modelling of the free-radical crosslinking of PDMS rubber in the presence of TEMPO nitroxidecitations
- 2009Viscoelasticity and mechanical properties of reactive PVC plastisolscitations
- 2009Synthesis and rheology of biodegradable poly(glycolic acid) prepared by melt ring opening
- 2009Synthesis and Rheology of Biodegradable Poly(glycolic acid) Prepared by Melt Ring-Opening Polymerization of Glycolide
- 2009Morphology development in thermoplastic vulcanizates (TPV): Dispersion mechanisms of a pre-crosslinked EPDM phasecitations
- 2009Cross-Linking Control of PDMS Rubber at High Temperatures Using TEMPO Nitroxidecitations
- 2009Uneven distribution of nanoparticles in immiscible fluids: Morphology development in polymer blendscitations
- 2009Effect of radical grafting of tetramethylpentadecane and polypropylene on carbon nanotubes' dispersibility in various solvents and polypropylene matrixcitations
- 2008Thermoplastic nanocomposites by in situ synthesis of the inorganic phase under molten processing conditions
- 2008Viscoelasticity of randomly crosslinked EPDM networks
- 2008Immiscible polymer blends stabilized with nano-silica particles: Rheology and effective interfacial tension
- 2008Migration of nanosilica particles in polymer blends
- 2008Free radical polymerization of glycidyl methacrylate in plasticized poly(vinyl chloride)
- 2008Melt rheology of organoclay and fumed silica nanocomposites
- 2007Morphology and rheology of immiscible polymer blends filled with silica nanoparticles
- 2007From conductive polymer composites with controlled morphology to smart materials
- 2007Preparation by reactive processing of in situ silica or silicoaluminate / thermoplastic nanocomposites by sol-gel method without solvent
- 2007Reactive Processing of Thermoplastic Polymers: A Review of the Fundamental Aspectscitations
- 2007Characterization and modelling of diffusion and reaction of low molecular weight reactants in molten polymer
- 2007Rheology and gelation kinetics of PVC plastisols
- 2005Viscoelastic properties and morphological characterization of silica/polystyrene nanocomposites synthesized by nitroxide-mediated polymerizationcitations
Places of action
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article
In situ coupled mechanical/electrical/WAXS/SAXS investigations on ethylene propylene diene monomer resin/carbon black nanocomposites
Abstract
International audience ; In situ coupled mechanical/electrical/WAXS/SAXS investigations on EPDM-based composite materials filled with carbon black (CB) have been performed under uniaxial tensile stretching. The time-resolved correlation between the electrical conductivity and the microstructural state of the composite reveals the mechanisms governing the structure/properties relationships with increasing deformation: orientation of the EPDM chains with reorganization of the CB network and ultimately, nano-cavitation. This involvement of different microstructural phenomena offers a comprehensive picture of the mechanisms underlying the non-monotonic evolution of the electrical conductivity with strain. At large deformations, the formation of nanovoids preceding the material fracture induces by a significant decrease in conductivity. Our study thus brings new light on the conductivity/strain relationships of carbon black filled elastomers. We envision potential applications in developing smart rubber materials where microstructural changes preceding material rupture can be monitored in situ by coupled electrical measurements.