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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Escher, B.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (10/10 displayed)
- 2020Phase formation of a biocompatible Ti-based alloy under kinetic constraints studied via in-situ high-energy X-ray diffraction
- 2019Stability of the B2 CuZr phase in Cu-Zr-Al-Sc bulk metallic glass matrix compositescitations
- 2017Structure of glassy Cu<inf>47.5</inf>Zr<inf>47.5</inf>Ag<inf>5</inf> investigated with neutron diffraction with isotopic substitution, X-ray diffraction, EXAFS and reverse Monte Carlo simulationcitations
- 2017Mapping the cyclic plastic zone to elucidate the mechanisms of crack tip deformation in bulk metallic glassescitations
- 2017Influence of the Ag concentration on the medium-range order in a CuZrAlAg bulk metallic glasscitations
- 2016Mapping of residual strains around a shear band in bulk metallic glass by nanobeam X-ray diffractioncitations
- 2016Influence of Ag and Co additions on glass-forming ability, thermal and mechanical properties of Cu–Zr–Al bulk metallic glassescitations
- 2015Structural features of plastic deformation in bulk metallic glassescitations
- 2015Atomic structure and formation of CuZrAl bulk metallic glasses and compositescitations
- 2014Microstructural Evolution and Mechanical Behaviour of Metastable Cu-Zr-Co Alloyscitations
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article
Influence of Ag and Co additions on glass-forming ability, thermal and mechanical properties of Cu–Zr–Al bulk metallic glasses
Abstract
In this study, the effect different amounts of Ag and Co have on thermalstability, phase formation and mechanical properties of theglass-forming alloys (Cu<sub>0.5</sub>Zr<sub>0.5</sub>)<sub>95−x−y</sub>Al<sub>5</sub>Ag<sub>x</sub>Co<sub>y</sub> (2≤x≤5 and 0≤y≤2) and Cu<sub>47.5−y</sub>Zr<sub>47.5</sub>Al<sub>5</sub>Co<sub>y</sub>(0≤y≤2) was investigated, respectively. The addition of Ag increasesthe glass-forming ability (GFA) of the alloys by enhancing the stabilityof the undercooled melt and by simultaneously reducing the stability ofthe B2 CuZr high-temperature phase. Co instead, has the oppositeeffect. It leads to an increased thermal stability of the B2 phase, aswell as a decreased stability of the undercooled melt and, consequently,lowers the GFA of the alloys. Moreover, a metastable big cube phaseprecipitates in some alloys stabilized by oxygen, which is introducedduring casting. There is a strong interdependence between the phaseformation and the tendency of the present alloys to vitrify. Thiscorrelation can be captured by the K-parameter (Song et al. 2011 [1])calculated from the respective transformation temperatures. The plasticstrain of the present ternary, quaternary and quinary alloys reflectsthe GFA as well: the higher the tendency to form a glass, the smallerthe plastic strain. Once B2 crystals precipitate in the glass, theplasticity is enhanced significantly.