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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Löschner, Katrin
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (7/7 displayed)
- 2024Validation of a Method for Surveillance of Nanoparticles in Mussels Using Single-Particle Inductively Coupled Plasma-Mass Spectrometrycitations
- 2023Vertical distribution of inorganic nanoparticles in a Norwegian fjordcitations
- 2022Analytical and toxicological aspects of nanomaterials in different product groupscitations
- 2020The presence of iron oxide nanoparticles in the food pigment E172citations
- 2015Feasibility of the development of reference materials for the detection of Ag nanoparticles in food: neat dispersions and spiked chicken meatcitations
- 2011Distribution of silver in rats following 28 days of repeated oral exposure to silver nanoparticles or silver acetatecitations
- 2004Line pattern in plasma polymer films with embedded gold and silver nanoparticles by irradiation with ultrashort laser pulses
Places of action
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article
Vertical distribution of inorganic nanoparticles in a Norwegian fjord
Abstract
<p>Due to the analyticalchallenges of detecting and quantifying nanoparticles in seawater, thedata on distributions of NPs in the marine environment is limited toqualitative studies or by ensemble measurements subject to variousanalytical artifacts. Single particle inductively coupled plasma massspectrometry (SP-ICP-MS) allows determination of individual inorganicNPs at environmentally relevant concentrations, yet only few studieshave been conducted on selected elements in surface sea water. Here, asequential multi-element screening method was developed and implementedto provide a first survey of the horizontal and vertical distributionsof inorganic nanoparticles and trace elements in a pristine Norwegianfjord prospect for submarine tailings deposition. Statistical control offalse-positive detections while minimizing the size detection limit wasensured using a novel raw signal processing. Scanning electronmicroscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS) gaveconfirmative and qualitative information regarding particle morphologyand composition. Following SP-ICP-MS screening for particles of 16elements, particulate Al, Fe, Mn, Pb, Si and Ti were found anddetermined to mass concentrations in ng/L of 1–399, 1–412, below limitof detection (<LOD) - 269, <LOD - 1, <LOD - 1981 and <LOD -127 ng/L with particle number concentrations up to 10<sup>8</sup>particles per liter. Total metals concentrations were at least an orderof magnitude higher, at concentrations in μg/L of 1–12 for Al, 2–13 forFe, 0.3–11 Mn, 0.02–0.5 for Pb, 46 to 318 Si and 0.04–0.4 for Ti. Astrong depth dependence was observed for both trace elements andparticles with concentrations increasing with depth. Our results providea baseline for the fjord and new data on environmental levels of bothtotal metals and metal containing nanoparticles including the verticaland horizontal distribution of natural nanoparticles.</p>