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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Zaghib, K.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (16/16 displayed)
- 2020On high-temperature evolution of passivation layer in Li–10 wt % Mg alloy via in situ SEM-EBSDcitations
- 2016Smart materials for energy storage in Li-ion batteriescitations
- 2014Surface modification of positive electrode materials for lithium-ion batteriescitations
- 2013Surface Control and Multi-composite Cathodes
- 2013Polypyrrole-covered MnO2 as Electrode Material for Supercapacitorcitations
- 2012Crystallinity of nano C-LiFePO4 prepared by the polyol processcitations
- 2011In-situ HRTEM Synthesis Observation of Nanostructured LiFePO4
- 2011Study of the surface modification of LiNi1/3Co1/3Mn1/3O2 cathode material for lithium ion battery
- 2009Synthesis, characterization and electrochemical properties of a novel triphosphate LiFe2P3O10citations
- 2009Study of the Li-insertion / extraction process in LiFePO4/FePO4citations
- 2008Surface Effects on the Physical and Electrochemical Properties of Thin LiFePO4 Particles
- 2007Mechanism of the Fe Reduction at Low Temperature for LiFePO Synthesis from a Polymeric Additive
- 2007Pulsed-laser deposited LiNi0.8Co0.15Al0.05O2 thin films for application in microbatteriescitations
- 2007Growth and electrochemical properties of Li-Ni-Co-Al oxide filmscitations
- 2007Mechanism of the Fe3+ reduction at low temperature for LiFePO4 synthesis from a polymeric additivecitations
- 2006Structure and insertion properties of disordered and ordered LN0.5Mn1.5O4 spinels prepared by wet chemistrycitations
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article
Crystallinity of nano C-LiFePO4 prepared by the polyol process
Abstract
Size and shape-tuned LiFePO4 nano-platelets were prepared by the polyol process to examine the effect of their microstructure on their electrochemical performance when coated by a thin carbon layer. The materials were characterized by X-ray diffraction, scanning and transmission electron microscopy, magnetic susceptibility, Fourier transform infrared and Raman spectroscopy. The crystallinity, as well as the size of the particles, depends on the nature of the solvent that is used, and also on the rate of dilution. The electrochemical properties emphasize the role of antisite defects and the coherence length along the b-axis, i.e. along the Li channels. With an optimized choice of the synthesis parameters, the results showed that the orthorhombic olivine structure is retained even in crystals of few nanometers in width, a free of impurities. The high crystalline quality of the particles obtained in these optimized conditions lead to a good electrochemical performance of the nanocomposite C-LiFePO4 product as a cathode material for lithium-ion batteries, with a capacity 151 mAh g 1 at low C-rate, despite the presence of residual adsorbed polyol species that are found to be insulating.