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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Školáková, Andrea
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2024Exploring the microstructure, mechanical properties, and corrosion resistance of innovative bioabsorbable Zn-Mg-(Si) alloys fabricated via powder metallurgy techniquescitations
- 2024Exploring the microstructure, mechanical properties, and corrosion resistance of innovative bioabsorbable Zn-Mg-(Si) alloys fabricated via powder metallurgy techniquescitations
- 2024Advantages of rapid solidification over casting of Mg-0.4Zn-1Y alloycitations
- 2023Effect of Double-Step and Strain-Assisted Tempering on Properties of Medium-Carbon Steelcitations
- 2023A detailed mechanism of degradation behaviour of biodegradable as-ECAPed Zn-0.8Mg-0.2Sr with emphasis on localized corrosion attackcitations
- 2023Suppression of mechanical instability in bioabsorbable ultrafine-grained Zn through in-situ stabilization by ZnO nanodispersoidscitations
- 2022Investigation of tadalafil molecular arrangement in solid dispersions using inverse gas chromatography and Raman mappingcitations
- 2021Microstructure evolution and mechanical performance of ternary Zn-0.8Mg-0.2Sr (wt. %) alloy processed by equal-channel angular pressingcitations
- 2021Influence of Ceramic Particles Character on Resulted Properties of Zinc-Hydroxyapatite/Monetite Compositescitations
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article
Suppression of mechanical instability in bioabsorbable ultrafine-grained Zn through in-situ stabilization by ZnO nanodispersoids
Abstract
The issue of intrinsic microstructural and mechanical instability of Zn-based metals limits their expansion in potential applications of bioresorbable stents and orthopedic fixators. A new concept of stabilization of Zn microstructure by a small fraction of nontoxic nano-metric ZnO dispersoids is proposed for the first time and demonstrated on the particular bioabsorbable model material. The effect of the ZnO dispersoids on post-processing microstructural stability, deformation and strengthening mechanisms, corrosion, and in -vitro biological behavior are pursued. The ZnO dispersoids arise in situ within deformed Zn structure during the consolidation of fine atomized Zn 99.99wt.% powder by hydro-extrusion. ZnO nanodispersoids (4.75 vol.%;-136 nm) form from passivating films pre-sent on Zn. They allow formation of ultrafine-grained Zn structure with an average grain size of-750 nm and its retention by Zener pinning action during annealing held at 100 degrees C. The model Zn + ZnO composite shows the superior mechanical properties than those reported for pure Zn materials. The utilized stabilization concept doesn't compromise corrosion and biological responses. Immersion of the Zn + ZnO in DMEM results in a corrosion rate, which complies with the desirable standard rate for biodegradable materials. Electrochemical tests suggest that the Zn + ZnO reaches a similar degradation rate after the first week of immersion and a more uniform corrosion behavior compared to the cast Zn reference. In-vitro cyto/genotoxicity assays performed using DMEM diluted extracts of the Zn + ZnO and cast Zn incubated with L929 cells yield in comparable and non-toxic responses. The presence of ZnO dispersoids induces a small but still significant bacteriostatic activity.(c) 2023 The Author(s). Published by Elsevier B.V. This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).