Materials Map

Discover the materials research landscape. Find experts, partners, networks.

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The Materials Map is an open tool for improving networking and interdisciplinary exchange within materials research. It enables cross-database search for cooperation and network partners and discovering of the research landscape.

The dashboard provides detailed information about the selected scientist, e.g. publications. The dashboard can be filtered and shows the relationship to co-authors in different diagrams. In addition, a link is provided to find contact information.

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Materials Map under construction

The Materials Map is still under development. In its current state, it is only based on one single data source and, thus, incomplete and contains duplicates. We are working on incorporating new open data sources like ORCID to improve the quality and the timeliness of our data. We will update Materials Map as soon as possible and kindly ask for your patience.

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in Cooperation with on an Cooperation-Score of 37%

Topics

Publications (4/4 displayed)

  • 2013Characterization of chitosan-magnesium aluminum silicate nanocomposite films for buccal delivery of nicotine25citations
  • 2011Novel chitosan-magnesium aluminum silicate nanocomposite film coatings for modified-release tablets38citations
  • 2010Chitosan-magnesium aluminum silicate nanocomposite films43citations
  • 2008Chitosan-magnesium aluminum silicate composite dispersions52citations

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Chart of shared publication
Pongjanyakul, Thaned
4 / 7 shared
Gordon, Keith C.
1 / 14 shared
Rades, Thomas
4 / 107 shared
Puttipipatkhachorn, Satit
4 / 6 shared
Strachan, Clare J.
1 / 10 shared
Chart of publication period
2013
2011
2010
2008

Co-Authors (by relevance)

  • Pongjanyakul, Thaned
  • Gordon, Keith C.
  • Rades, Thomas
  • Puttipipatkhachorn, Satit
  • Strachan, Clare J.
OrganizationsLocationPeople

article

Chitosan-magnesium aluminum silicate composite dispersions

  • Pongjanyakul, Thaned
  • Rades, Thomas
  • Khunawattanakul, Wanwisa
  • Puttipipatkhachorn, Satit
Abstract

Composite dispersions of chitosan (CS), a positively charged polymer, and magnesium aluminum silicate (MAS), a negatively charged clay, were prepared and rheology, flocculate size and zeta potential of the CS-MAS dispersions were investigated. High and low molecular weights of CS (HCS and LCS, respectively) were used in this study. Moreover, the effects of heat treatment at 60 degrees C on the characteristics of the CS-MAS dispersions and the zeta potential of MAS upon addition of CS at different pHs were examined. Incorporation of MAS into CS dispersions caused an increase in viscosity and a shift of CS flow type from Newtonian to pseudoplastic flow with thixotropic properties. Heat treatment brought about a significant decrease in viscosity and hysteresis area of the composite dispersions. Microscopic studies showed that flocculation of MAS occurred after mixing with CS. The size and polydispersity index of the HCS-MAS flocculate were greater than those of the LCS-MAS flocculate. However, a narrower size distribution and the smaller size of the HCS-MAS flocculate were found after heating at 60 degrees C. Zeta potentials of the CS-MAS flocculates were positive and slightly increased with increasing MAS content. In the zeta potential studies, the negative charge of the MAS could be neutralized by the addition of CS. Increasing the pH and molecular weight of CS resulted in higher CS concentrations required to neutralize the charge of MAS. These findings suggest that the electrostatic interaction between CS and MAS caused a change in flow behavior and flocculation of the composite dispersions, depending on the molecular weight of CS. Heat treatment affected the rheological properties and the flocculate size of the composite dispersions. Moreover, pH of medium and molecular weight of CS influence the zeta potential of MAS.

Topics
  • dispersion
  • polymer
  • Magnesium
  • Magnesium
  • aluminium
  • composite
  • viscosity
  • molecular weight
  • polydispersity
  • liquid chromatography