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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Millange, Franck
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (12/12 displayed)
- 2021New hybrid MOF/polymer composites for the photodegradation of organic dyescitations
- 2016Iodine sequestration by thiol-modified MIL-53(Al)citations
- 2015Metal-organic frameworks from divalent metals and 1,4-benzenedicarboxylate with bidentate pyridine-N-oxide co-ligandscitations
- 2015Metal-organic frameworks from divalent metals and 1,4-benzenedicarboxylate with bidentate pyridine-N-oxide co-ligandscitations
- 2015Metal–Organic Frameworks from Divalent Metals and 1,4-Benzenedicarboxylate with Bidentate Pyridine- N -oxide Co-ligandscitations
- 2013Isomorphous Substitution in a Flexible Metal–Organic Framework: Mixed-Metal, Mixed-Valent MIL-53 Type Materialscitations
- 2013Adsorption of N/S heterocycles in the flexible metal–organic framework MIL-53(FeIII) studied by in situ energy dispersive X-ray diffractioncitations
- 2012Liquid-Phase Adsorption and Separation of Xylene Isomers by the Flexible Porous Metal-Organic Framework MIL-53(Fe)citations
- 2007Mixed-Valence Li/Fe-Based Metal-Organic Frameworks with Both Reversible Redox and Sorption Propertiescitations
- 2006Synthesis of MIL-102, a chromium carboxylate metal-organic framework, with gas sorption analysiscitations
- 2006A new isoreticular class of metal-organic-frameworks with the MIL-88 topology
- 2006An EXAFS study of the formation of a nanoporous metal-organic framework: evidence for the retention of secondary building units during synthesis
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article
New hybrid MOF/polymer composites for the photodegradation of organic dyes
Abstract
Hybrid Metal Organic-Frameworks (MOF)/polymer materials have gathered many researcher's consideration thanks to their varied functionalities and high processability. Herein, Metal Organic Frameworks (MOFs) have been successfully incorporated into an acrylate polymer network by photopolymerization upon mild visible light irradiation at 405 nm. The synthesized MOF/polymer composites were very efficient for Acid Black removal from water reaching 96% of decomposition after 30 and 45 min of UV-Lamp irradiation in the presence of MIL-53(Cr)/polymer and HKUSTI-1(Cu)/polymer composites, respectively. Probing further, the photo-composites were characterized by several techniques including Thermogravimetric Analysis (TGA), Fourier-Transform Infrared Spectroscopy (FTIR), Scanning Electron Microscopy (SEM), Transmission Electron Microscopy (TEM), Energy-dispersive X-ray 2 analyses (EDX), X-Ray Diffraction analysis (DRX), Brunauer, Emmett and Teller (BET) specific surface area, Atomic Force Microscopy (AFM), Dynamic Mechanical Analysis (DMA) and UV-Visible diffuse reflectance spectroscopy. The different methods used to characterized the MOF-containing polymers revealed these polymers to exhibit a high rigidity, an excellent thermal stability, an interesting band gap energy as well as an exceptional stability after their reuse for many photocatalytic treatment cycles.