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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Cesiulis, Henrikas
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Electrodeposited Fe on Cu foam as advanced fenton reagent for catalytic mineralization of methyl orangecitations
- 2021Mechanical, magnetic and magnetostrictive properties of porous Fe-Ga films prepared by electrodepositioncitations
- 2019Nanocrystalline electrodeposited Fe-W/Al2O3 Composites : effect of Alumina Sub-microparticles on the mechanical, tribological, and corrosion propertiescitations
- 2018Enhanced mechanical properties and microstructural modifications in electrodeposited Fe-W alloys through controlled heat treatmentscitations
- 2018Chemical, electrochemical and tribological study of various olive oils and their behaviour on steelcitations
- 2018Chemical, electrochemical and tribological study of various olive oils and their behaviour on steel ; Įvairių alyvuogių aliejų cheminiai, elektrocheminiai bei tribologiniai tyrimai ir jų elgsena ant plienocitations
- 2018In-depth characterization of as-deposited and annealed Fe-W coatings electrodeposited from glycolate-citrate plating bathcitations
- 2018Mapping of magnetic and mechanical properties of Fe-W alloys electrodeposited from Fe(III)-based glycolate-citrate bathcitations
- 2016Toward uniform electrodeposition of magnetic Co-W mesowires arrays : direct versus pulse current depositioncitations
- 2009Tribologic properties of vegetable and mineral oils with suspended nanoparticles
- 2009Tribological properties of mineral oils modified with metallic nano-particles
- 2008Influence of fluor-oligomers on the structural and tribological properties of steel surface at the rolling friction
- 2007Failure analysis by indentation test of electrodeposited nanocrystalline CO-W and FE-W thin films
- 2007Mechanical behaviour of electrochemically manufactured thin Co-W-PFealloy coatings
Places of action
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article
In-depth characterization of as-deposited and annealed Fe-W coatings electrodeposited from glycolate-citrate plating bath
Abstract
Fe-W coatings with 4, 16 and 24 at.% of W were electrodeposited under galvanostatic conditions from a new environmental friendly Fe(III)-based glycolate-citrate bath. This work aims to find correlations between composition including the light elements, internal structure of the electrodeposited Fe-W alloys and functional properties of material. The obtained alloys were characterized by Glow Discharge Optical Emission Spectrometry (GD-OES), Scanning Electron Microscopy (SEM) with Energy Dispersive X-ray Spectroscopy (EDS), Transmission Electron Microscopy (TEM), and X-ray Diffraction (XRD). Compositional depth profiles of 10 μm thick coatings obtained by GD-OES show that the distribution of metals is uniform along the entire film thickness, while SEM imaging depicted the presence of cracks and O- and W-rich areas inside the Fe-W coating with 4 at.% W. In the samples with 16 and 24 at.% of W, oxygen and hydrogen are present mostly at the surface about 1 μm from the top while traces of carbon are distributed within the entire coatings. With increasing W content, the structure of the coatings changes from nanocrystalline to amorphous which was shown by XRD and TEM analysis. Also, the surface of coatings becomes smoother and brighter, that was explained based on the local adsorption of intermediates containing iron and tungsten species. Annealing experiments coupled with XRD analysis show that the thermal stability of Fe-W alloys increases when the W content increases, i.e. the coating with 24 at.% W retains the amorphous structure up to 600 °C, where a partially recrystallized structure was observed. Upon recrystallization of the amorphous samples the following crystalline phases are formed: α-Fe, Fe2W, Fe3W3C, Fe6W6C, and FeWO4. Hence, the Fe-W coatings with higher W content (>25 at.%) can be considered as suitable material for high temperature applications.