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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Iwaniszyn, Marzena
Institute of Chemical Engineering
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2016Cu SSZ-13 zeolite catalyst on metallic foam support for SCR of NOx with ammonia: Catalyst layering and characterisation of active sitescitations
- 2015Selective catalytic reduction of nitrogen oxides on a zeolite catalyst deposited on metallic foam carrier
- 2012Coupled engineering and chemical approach to the design of a catalytic structured reactor for combustion of VOCs : cobalt oxide catalyst on knitted wire gauzescitations
- 2012Coupled engineering and chemical approach to the design of a catalytic structured reactor for combustion of VOCs: Cobalt oxide catalyst on knitted wire gauzescitations
Places of action
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article
Coupled engineering and chemical approach to the design of a catalytic structured reactor for combustion of VOCs: Cobalt oxide catalyst on knitted wire gauzes
Abstract
A structured reactor was built from stacked catalytic knitted wire gauzes. The cobalt oxide catalyst was deposited on the wire gauze surface using the plasma enhanced metal-organic chemical vapour deposition method. The Raman scattering, electron diffraction and photoelectron emission analyses of the catalyst surface evidenced the formation of a cobalt oxide spinel with crystallites of about 5 nm. The results of kinetic studies of VOC combustion (using n-hexane as a probe molecule) performed in a gradientless reactor allowed determining the reaction order and activation energy for this catalytic reaction. It has been proved that reaction follows first order kinetics. Two reactor models (plug-flow and plug-dispersion) were compared and the simpler plug-flow one is recommended due to the negligible influence of axial dispersion. Experiments were performed in a large laboratory reactor (temperature up to 873 K. gas stream up to 10 m(3)/h STP) for catalytic conversion of VOCs (n-hexane). The model validation has shown satisfactory accuracy with maximum and average errors of 12% and 4%, respectively.