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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Siuzdak, Katarzyna
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (13/13 displayed)
- 2022Temperature-controlled nanomosaics of AuCu bimetallic structure towards smart light managementcitations
- 2022The Anodization of Thin Titania Layers as a Facile Process towards Semitransparent and Ordered Electrode Materialcitations
- 2021Exploring the effect of BN and B-N bridges on the photocatalytic performance of semiconductor heterojunctions: Enhancing carrier transfer mechanismcitations
- 2021Study of nanostructured ultra-refractory Tantalum-Hafnium-Carbide electrodes with wide electrochemical stability windowcitations
- 2021Study of nanostructured ultra-refractory Tantalum-Hafnium-Carbide electrodes with wide electrochemical stability windowcitations
- 2020Enhancing photocatalytic performance and solar absorption by schottky nanodiodes heterojunctions in mechanically resilient palladium coated TiO2/Si nanopillars by atomic layer depositioncitations
- 2020Enhancing photocatalytic performance and solar absorption by schottky nanodiodes heterojunctions in mechanically resilient palladium coated TiO2/Si nanopillars by atomic layer depositioncitations
- 2020The pulsed laser ablation synthesis of colloidal iron oxide nanoparticles for the enhancement of TiO<inf>2</inf> nanotubes photo-activitycitations
- 2020Spectacular Oxygen Evolution Reaction Enhancement through Laser Processing of the Nickel-Decorated Titania Nanotubescitations
- 2019Photoelectrochemically Active N-Adsorbing Ultrathin TiO <inf>2</inf> Layers for Water-Splitting Applications Prepared by Pyrolysis of Oleic Acid on Iron Oxide Nanoparticle Surfaces under Nitrogen Environmentcitations
- 2018Titania nanotubes modified by a pyrolyzed metal-organic framework with zero valent iron centers as a photoanode with enhanced photoelectrochemical, photocatalytical activity and high capacitancecitations
- 2017Silicon/TiO<inf>2</inf> core-shell nanopillar photoanodes for enhanced photoelectrochemical water oxidationcitations
- 2017High Electrocatalytic Response of a Mechanically Enhanced NbC Nanocomposite Electrode Toward Hydrogen Evolution Reactioncitations
Places of action
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article
Exploring the effect of BN and B-N bridges on the photocatalytic performance of semiconductor heterojunctions: Enhancing carrier transfer mechanism
Abstract
Several strategies are currently available to improve the photocatalytic response and performance of materials and devices. Despite this, the most common strategies are still based on the promotion of efficient carrier transfer/lifetime of photo-exited electrons and bandgap tailoring. In this work, we present conclusive experimental evidence of the synergistic effect of Boron Nitride (BN) and B-N bridges on the carrier transfer efficiency of photogenerated species. We present a simple method for exploiting both approaches by the incorporation of B-N bridges on TiO2/ZnO heterojunctions by Atomic Layer Deposition (ALD). We show the improved lifetime of holes by the integration of B-N bridges, as shown by the very low first-order recombination times 3.4±1.2 ns−1, and the superior photoresponse of the composites, with a strong increment of 170% observed in transient photocurrent studies and supported by the incident photon to current efficiency. Also, the TiO2/ZnO/BN heterojunction presents an 82% in photodegradation of contaminants (k=7.84*10−3 min−1). Finally, we provide experimental evidence of the hole extracting role of BN and bring a general strategy for integration of B-N bridges by ALD conformal coating capabilities. We believe that the results open up the possibility for exploitation in several architectures, materials, and devices by in-situ preparation of efficient carrier transfer layers by ALD.