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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Raza, Rizwan
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (14/14 displayed)
- 2022Improved self-consistency and oxygen reduction activity of CaFe2O4 for protonic ceramic fuel cell by porous NiO-foam supportcitations
- 2022Influence of Sintering Temperature on the Structural, Morphological, and Electrochemical Properties of NiO-YSZ Anode Synthesized by the Autocombustion Routecitations
- 2021Studies of electrical and optical properties of cadmium‐doped zinc oxide for energy conversion devicescitations
- 2021Promoted electrocatalytic activity and ionic transport simultaneously in dual functional Ba0.5Sr0.5Fe0.8Sb0.2O3-δ-Sm0.2Ce0.8O2-δ heterostructurecitations
- 2021Electrochemical Investigations of BaCe0.7-xSmxZr0.2Y0.1O3-δ Sintered at a Low Sintering Temperature as a Perovskite Electrolyte for IT-SOFCscitations
- 2021Evaluation of BaCo0.Fe-4(0).4Zr0.2-xNixO3-delta perovskite cathode using nickel as a sintering aid for IT-SOFCcitations
- 2020Functional ceria-based nanocomposites for advanced low-temperature (300–600 °C) solid oxide fuel cell : A comprehensive reviewcitations
- 2019Tri-doped ceria (M0.2Ce0.8O2-δ, M= Sm0.1 Ca0.05 Gd0.05) electrolyte for hydrogen and ethanol-based fuel cellscitations
- 2018Electrochemical and thermal characterization of doped ceria electrolyte with lanthanum and zirconiumcitations
- 2018In Vitro Cytotoxicity and Morphological Assessments of GO-ZnO against the MCF-7 Cells: Determination of Singlet Oxygen by Chemical Trappingcitations
- 2015Significance enhancement in the conductivity of core shell nanocomposite electrolytes
- 2015Synthesis of Ba0.3Ca0.7Co0.8Fe0.2O3-δ composite material as novel catalytic cathode for ceria-carbonate electrolyte fuel cellscitations
- 2013A new energy conversion technology based on nano-redox and nano-device processescitations
- 2011Functional nanocomposites for advanced fuel cell technology and polygeneration
Places of action
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article
Promoted electrocatalytic activity and ionic transport simultaneously in dual functional Ba0.5Sr0.5Fe0.8Sb0.2O3-δ-Sm0.2Ce0.8O2-δ heterostructure
Abstract
<p>Structural doping is often used to prepare materials with high oxygen-ion conductivity and electrocatalytic function, but its wider application in solid oxide fuel cells (SOFCs) is still a major challenge. Here, a novel approach to developing materials with fast ionic conduction and high electrocatalytic activity is reported. A semiconductor-ionic heterostructure of perovskite Ba<sub>0.5</sub>Sr<sub>0.5</sub>Fe<sub>0.8</sub>Sb<sub>0.2</sub>O<sub>3-δ</sub> (BSFSb) and fluorite structure Sm<sub>0.2</sub>Ce<sub>0.8</sub>O<sub>2-δ</sub> (SDC) is developed. The BSFSb-SDC heterostructure exhibits a high ionic conductivity >0.1 S cm<sup>−1</sup> (vs 0.01 S cm<sup>−1</sup> of SDC) and achieves a remarkable fuel cell performance (>1000 mWcm<sup>−2</sup>) at 550 °C. It was found that the BSFSb-SDC has both electrolyte and electrode (cathode) functions with enhanced ionic transport and electrocatalytic activity simultaneously. When using BSFSb-SDC as an electrolyte, the interface energy-band reconstruction and charge transfer at particle level forming a built-in electric field (BIEF) and it make electronic confinement. The BIEF originates from the potential gradient due to differences in the electron density of BSFSb and SDC particles/grains facilitates ionic conduction at the interface of the BSFSb and SDC particles. This work provides a new insight in designing functional materials with high ionic conductivity and electrocatalytic function, which can be used both for energy conversion and storage device.</p>