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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Dam, Bernard
Delft University of Technology
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (23/23 displayed)
- 2023Tuning the Properties of Thin-Film TaRu for Hydrogen-Sensing Applicationscitations
- 2020Metallurgical Synthesis of Mg2FexSi1- x Hydridecitations
- 2019Metal-polymer hybrid nanomaterials for plasmonic ultrafast hydrogen detectioncitations
- 2019Metal-polymer hybrid nanomaterials for plasmonic ultrafast hydrogen detectioncitations
- 2019Effect of the addition of zirconium on the photochromic properties of yttrium oxy-hydridecitations
- 2019Suppressing H 2 Evolution and Promoting Selective CO 2 Electroreduction to CO at Low Overpotentials by Alloying Au with Pdcitations
- 2019Suppressing H2 Evolution and Promoting Selective CO2 Electroreduction to CO at Low Overpotentials by Alloying Au with Pdcitations
- 2018Elastic versus Alloying Effects in Mg-Based Hydride Filmscitations
- 2017Enhancement of Destabilization and Reactivity of Mg Hydride Embedded in Immiscible Ti Matrix by Addition of Crcitations
- 2017Photochromism of rare-earth metal-oxy-hydridescitations
- 2016Interface and strain effects on the H-sorption thermodynamics of size-selected Mg nanodotscitations
- 2016Photoelectrochemical water splitting with porous α-Fe2O3 thin films prepared from Fe/Fe-oxide nanoparticlescitations
- 2016Amorphous Metal-Hydrides for Optical Hydrogen Sensingcitations
- 2015Destabilization of Mg Hydride by Self-Organized Nanoclusters in the Immiscible Mg-Ti System
- 2012Optical hydrogen sensors based on metal-hydridescitations
- 2012Combined XPS and first principle study of metastable Mg-Ti thin filmscitations
- 2011Thin film metal hydrides for hydrogen storage applicationscitations
- 2010X-ray photoelectron spectroscopy study of MgH2 thin films grown by reactive sputteringcitations
- 2009Lightweight sodium alanate thin films grown by reactive sputteringcitations
- 2009Hydrogenography of PdHx thin films: Influence of H-induced stress relaxation processescitations
- 2008Optimization of Mg-based fiber optic hydrogen detectors by alloying the catalystcitations
- 2006The growth-induced microstructural origin of the optical black state of Mg 2 NiH x thin films
- 2006Structural and optical properties of MgxAl1-xH y gradient thin filmscitations
Places of action
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article
Combined XPS and first principle study of metastable Mg-Ti thin films
Abstract
<p>X-ray photoelectron spectroscopy (XPS) was employed to investigate Mg <sub>80</sub>Ti <sub>20</sub> thin film samples prepared by magnetron sputtering and density functional theory (DFT) calculations were performed on atomistic models with similar stoichiometry. As Ti is known to be immiscible in Mg, the microstructure and atomic distribution of Mg-Ti thin films are not fully understood. In this work, it was shown by DFT calculations that the density of states (DOS) depends strongly on whether Ti is arranged in nano-clusters or if it is distributed quasi-randomly. The calculated DOS was compared to valence band spectra measured by XPS, as a new way of indirectly probing short-range order of such thin films. The XPS results of Mg <sub>80</sub>Ti <sub>20</sub> were found to correspond best with the DOS calculated for the nano-cluster model, supporting the view that Ti forms small clusters in such sputtered thin films.</p>