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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Diplas, S.
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (4/4 displayed)
- 2023Accelerated material development for laser powder-bed fusion using the arc melting processcitations
- 2021Process–Structure–Property Relationship in FeCoNiAlxMnx Complex Concentrated Alloys Processed by Additive Manufacturingcitations
- 2012Combined XPS and first principle study of metastable Mg-Ti thin filmscitations
- 2010XPS characterisation of the interface between anode and electrolyte in a proton conducting solid oxide fuel cellcitations
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article
XPS characterisation of the interface between anode and electrolyte in a proton conducting solid oxide fuel cell
Abstract
<p>In this work, we deposited by pulsed laser deposition nanometric layers of proton conducting calcium-doped lanthanum niobate (La<sub>0.995</sub>Ca <sub>0.oo5</sub>NbO<sub>4</sub>) on nickel substrates in order to fabricate model structures of the electrolyte-anode interface present in potential proton conducting solid oxide fuel cells (PC-SOFC). Characterisation by XPS of in situ reduced samples indicates the absence of chemical reaction between lanthanum niobate and nickel, confirming their reciprocal chemical stability. A peak shift to higher binding energies is observed for the elements of the electrolyte material after exposure to reducing atmosphere for several hours at a typical operating temperature for PC-SOFC. This shift is attributed to the formation of a space charge layer in the oxide at the interface with metallic nickel.</p>