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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Schmuki, Patrik
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (29/29 displayed)
- 2023Activation of Osmium by the Surface Effects of Hydrogenated TiO2 Nanotube Arrays for Enhanced Hydrogen Evolution Reaction Performancecitations
- 2023Single Atoms in Photocatalysis: Low Loading Is Good Enough!citations
- 2023TiO2 nanotube arrays decorated with Ir nanoparticles for enhanced hydrogen evolution electrocatalysis
- 2023Metastable Ni(I)-TiO2–x Photocatalysts: Self-Amplifying H2 Evolution from Plain Water without Noble Metal Co-Catalyst and Sacrificial Agentcitations
- 2023Fluorine Aided Stabilization of Pt Single Atoms on TiO2 Nanosheets and Strongly Enhanced Photocatalytic H2 Evolutioncitations
- 2022A Few Pt Single Atoms Are Responsible for the Overall Co‐Catalytic Activity in Pt/TiO <sub>2</sub> Photocatalytic H <sub>2</sub> Generationcitations
- 2022Comparison of the sputtered TiO2 anatase and rutile thin films as electron transporting layers in perovskite solar cellscitations
- 2022Amorphous NiCu Thin Films Sputtered on TiO2 Nanotube Arrays: A Noble‐Metal Free Photocatalyst for Hydrogen Evolutioncitations
- 2022Light‐Induced Agglomeration of Single‐Atom Platinum in Photocatalysiscitations
- 2022A facile “dark”-deposition approach for Pt single‐atom trapping on facetted anatase TiO2 nanoflakes and use in photocatalytic H2 generationcitations
- 2022Band gap and Morphology Engineering of Hematite Nanoflakes from an Ex Situ Sn Doping for Enhanced Photoelectrochemical Water Splittingcitations
- 2022Inhibition of H2 and O2 Recombination: The Key to a Most Efficient Single‐Atom Co‐Catalyst for Photocatalytic H2 Evolution from Plain Watercitations
- 2021Comparison of the sputtered TiO2 anatase and rutile thin films as electron transporting layers in perovskite solar cellscitations
- 2021Reduced grey brookite for noble metal free photocatalytic H2 evolutioncitations
- 2021Thermal Ramping Rate during Annealing of TiO2 Nanotubes Greatly Affects Performance of Photoanodescitations
- 2021Hydrogenated anatase TiO2 single crystals: defects formation and structural changes as microscopic origin of co-catalyst free photocatalytic H2 evolution activitycitations
- 2021Thermal Ramping Rate during Annealing of TiO<sub>2</sub> Nanotubes Greatly Affects Performance of Photoanodescitations
- 2021As a single atom Pd outperforms Pt as the most active co-catalyst for photocatalytic H2 evolutioncitations
- 2020Dewetting of PtCu Nanoalloys on TiO$_{2}$ Nanocavities Provides a Synergistic Photocatalytic Enhancement for Efficient H$_{2}$ Evolutioncitations
- 2020Multi-Leg TiO2 Nanotube Photoelectrodes Modified by Platinized Cyanographene with Enhanced Photoelectrochemical Performancecitations
- 2020Dewetting of PtCu Nanoalloys on TiO2Nanocavities Provides a Synergistic Photocatalytic Enhancement for Efficient H2Evolutioncitations
- 2020A Dewetted-Dealloyed Nanoporous Pt Co-Catalyst Formed on TiO2 Nanotube Arrays Leads to Strongly Enhanced Photocatalytic H-2 Productioncitations
- 2020A Dewetted-Dealloyed Nanoporous Pt Co-Catalyst Formed on TiO2 Nanotube Arrays Leads to Strongly Enhanced Photocatalytic H2 Productioncitations
- 2020Photo-Electrochemical Solar-to-Fuel Energy Conversion by Hematite-Based Photo-Anodes-The Role of 1D Nanostructuringcitations
- 2020High-performance hydrogen evolution electrocatalysis using proton-intercalated TiO2 nanotube arrays as interactive supports for Ir nanoparticlescitations
- 2019Photocatalysis with Reduced TiO2: From Black TiO2 to Cocatalyst-Free Hydrogen Productioncitations
- 2018TiO2 Nanotubes on Transparent Substrates: Control of Film Microstructure and Photoelectrochemical Water Splitting Performancecitations
- 2018A direct synthesis of platinum/nickel co-catalysts on titanium dioxide nanotube surface from hydrometallurgical-type process streamscitations
- 2010Controlling the adsorption kinetics via nanostructuring : Pd nanoparticles on TiO2 nanotubescitations
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article
Thermal Ramping Rate during Annealing of TiO<sub>2</sub> Nanotubes Greatly Affects Performance of Photoanodes
Abstract
<jats:sec><jats:label /><jats:p>Herein, highly ordered TiO<jats:sub>2</jats:sub> nanotube (NT) arrays on a Ti substrate is synthesized in a fluoride‐containing electrolyte, using the electrochemical anodization method, which yields amorphous oxide tubes. The effects of different thermal annealing profiles for the crystallization of the amorphous TiO<jats:sub>2</jats:sub> NTs are studied. It is found that the temperature ramping rate has a significant impact on the magnitude of the resulting photocurrents (incident photon‐to‐current conversion efficiency [IPCE]) from the tubes. No appreciable changes are observed in the crystal structure and morphology of the TiO<jats:sub>2</jats:sub> NTs for different annealing profiles (to a constant temperature of 450 °C). The electrochemical properties of the annealed TiO<jats:sub>2</jats:sub> NTs are investigated using intensity‐modulated photocurrent spectroscopy (IMPS), open‐circuit potential decay, and Mott–Schottky analysis. The results clearly show that the annealing ramping rate of 1 °C s<jats:sup>−1</jats:sup> leads to the highest IPCE performance. This beneficial effect can be ascribed to a most effective charge separation and electron transport (indicating the least amount of trapping states in the tubes). Therefore, the results suggest that controlling the annealing ramping rate is not only a key factor affecting the defect structure but also a powerful tool to tailor the physical properties, and photocurrent activity of TiO<jats:sub>2</jats:sub> NTs.</jats:p></jats:sec>