693.932 PEOPLE
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| Naji, M. |
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| Petrov, R. H. | Madrid |
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Wessling, Matthias
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Topics
Publications (35/35 displayed)
- 2024Electro‐Conductive Ti<sub>3</sub>C<sub>2</sub> MXene Multilayered Membranes: Dye Removal and Antifouling Performancecitations
- 2024Tubular and bio-based carbons as binder-free gas diffusion electrodes for heterogeneous electro-Fenton to remove micropollutantscitations
- 2023Tailoring Pore Networks – Gas Diffusion Electrodes via Additive Manufacturingcitations
- 2023Poly(aryl ether ketone) hollow fibers preparation with acid resistant spinneretscitations
- 2022Monolithic SiC supports with tailored hierarchical porosity for molecularly selective membranes and supported liquid-phase catalysiscitations
- 2022Monolithic SiC supports with tailored hierarchical porosity for molecularly selective membranes and supported liquid-phase catalysiscitations
- 2022On the Mixed Gas Behavior of Organosilica Membranes Fabricated by Plasma-Enhanced Chemical Vapor Deposition (PECVD)citations
- 2022Rotating microstructured spinnerets produce helical ridge membranes to overcome mass transfer limitationscitations
- 2022Organosilica coating layer prevents aging of a polymer with intrinsic microporositycitations
- 2020Stimuli-Responsive Zwitterionic Core-Shell Microgels for Antifouling Surface Coatingscitations
- 2020Tubular hollow fibre electrodes for CO2 reduction made from copper aluminum alloy with drastically increased intrinsic porosity
- 2020Steady-state electrochemical synthesis of HKUST-1 with polarity reversalcitations
- 2019High-Throughput Production of Micrometer Sized Double Emulsions and Microgel Capsules in Parallelized 3D Printed Microfluidic Devices
- 2019Layer-by-layer membrane modification allows scandium recovery by nanofiltrationcitations
- 2013Conjugated polymer particles : Towards self-assembling organic photonics
- 2013Challenges and advances in the field of self-assembled membranescitations
- 2012Fabrication of cell container arrays with overlaid surface topographiescitations
- 2012Fabrication of cell container arrays with overlaid surface topographiescitations
- 2012Towards a generic method for inorganic porous hollow fibers preparation with shrinkage-controlled small radial dimensions, applied to Al2O3, Ni, SiC, stainless steel, and YSZcitations
- 2011Hollow fiber ultrafiltration membranes with microstructured inner skincitations
- 2011Porous stainless steel hollow fiber membranes via dry-wet spinningcitations
- 2011Carbon nanofibers in catalytic membrane microreactorscitations
- 2011Thermoforming of film-based biomedical microdevicescitations
- 2011Porous stainless steel hollow fibers with shrinkage-controlled small radial dimensionscitations
- 2010Microstructured hollow fibers for ultrafiltrationcitations
- 2010Shrinkage effects during polmer phase separation on microfabricated moldscitations
- 2010Surface texturing inside ceramic macro/micro channelscitations
- 2010Polymeric microsieves via phase separation microfabricationcitations
- 2009Microcontact Printing of Dendrimers, Proteins, and Nanoparticles by Porous Stampscitations
- 2009Micropatterned polymer films by vapor-induced phase separation using permeable moldscitations
- 2007Morphology and Microtopology of Cation-Exchange Polymers and the Origin of the Overlimiting Currentcitations
- 2006Polymeric microsieves produced by phase separation micromoldingcitations
- 2006Fullerene-modified poly(2,6-dimethyl-1,4-phenylene oxide) gas separation membranes: Why binding is better than dispersing
- 2006Superhydrophobic Surfaces Having Two-Fold Adjustable Roughness Prepared in a Single Stepcitations
- 2005New replication technique for the fabrication of thin polymeric microfluidic devices with tunable porositycitations
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article
Organosilica coating layer prevents aging of a polymer with intrinsic microporosity
Abstract
<p>This study tracks the physical aging behavior of coated and uncoated ultra-thin poly(1-trimethylsilyl-1-propyne) (PTMSP) films on silicon wafers based on the refractive index using ellipsometry. The measured refractive index directly correlates with the free volume and hence the physical aging progression. Plasma-enhanced chemical vapor deposition (PECVD) creates coatings with different thicknesses and oxidation degrees onto PTMSP films. Compared to uncoated PTMSP films, the PECVD-coated films show a reduction of the refractive index increase of more than two orders of magnitude for less than 10 nm thin SiOx coatings. In contrast, SiOCH films show only a minor impact. The results reveal the superior physical aging behavior of PECVD-coated films compared to untreated PTMSP films.</p>