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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Malmström, Eva
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (8/8 displayed)
- 2024Poly(sobrerol methacrylate) Colloidal Inks Sprayed onto Cellulose Nanofibril Thin Films for Anticounterfeiting Applicationscitations
- 2023Optical properties of slot-die coated hybrid colloid/cellulose-nanofibril thin filmscitations
- 2023Branched polyesters from radical ring-opening polymerization of cyclic ketene acetals: synthesis, chemical hydrolysis and biodegradationcitations
- 2023Optical Properties of Slot‐Die Coated Hybrid Colloid/Cellulose‐Nanofibril Thin Filmscitations
- 2023Optical Properties of Slot‐Die Coated Hybrid Colloid/Cellulose‐Nanofibril Thin Filmscitations
- 2017Tailoring Dielectric Properties using Designed Polymer-Grafted ZnO Nanoparticles in Silicone Rubbercitations
- 2009Adhesion dynamics for cellulose nanocomposites.citations
- 2003Hyperbranched polymers as scaffolds for multifunctional reversible addition-fragmentation chain-transfer agentscitations
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article
Hyperbranched polymers as scaffolds for multifunctional reversible addition-fragmentation chain-transfer agents
Abstract
<p>Polydisperse hyperbranched polyesters were modified for use as novel multifunctional reversible addition-fragmentation chain-transfer (RAFT) agents. The polyester-core-based RAFT agents were subsequently employed to synthesize star polymers of n-butyl acrylate and styrene with low polydispersity (polydispersity index < 1.3) in a living free-radical process. Although the polyester-core-based RAFT agent mediated polymerization of n-butyl acrylate displayed a linear evolution of the number-average molecular weight (M<sub>n</sub>) up to high monomer conversions (>70%) and molecular weights [M<sub>n</sub> > 140,000 g mol<sup>-1</sup>, linear poly(methyl methacrylate) equivalents)], the corresponding styrene-based system reached a maximum molecular weight at low conversions (≈30%, M<sub>n</sub> = 45,500 g mol<sup>-1</sup>, linear polystyrene equivalents). The resulting star polymers were subsequently used as platforms for the preparation of star block copolymers of styrene and n-butyl acrylate with a polyester core with low polydispersities (polydispersity index < 1.25). The generated polystyrene-based star polymers were successfully cast into highly regular honeycomb-structured microarrays.</p>