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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Vancso, Gyula Julius
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Topics
Publications (10/10 displayed)
- 2023Designer Adhesives for Tough and Durable Interfaces in High-Performance Ti-Carbon PEKK Hybrid Jointscitations
- 2019Oscillating surfaces fueled by a continuous AC electric fieldcitations
- 2019Printing "smart" Inks of Redox-Responsive Organometallic Polymers on Microelectrode Arrays for Molecular Sensingcitations
- 2019Brush Swelling and Attachment Strength of Barnacle Adhesion Protein on Zwitterionic Polymer Films as a Function of Macromolecular Structurecitations
- 2017Synchrotron SAXS and Impedance Spectroscopy Unveil Nanostructure Variations in Redox-Responsive Porous Membranes from Poly(ferrocenylsilane) Poly(ionic liquid)scitations
- 2017Ion-Selective Ionic Polymer Metal Composite (IPMC) Actuator Based on Crown Ether Containing Sulfonated Poly(Arylene Ether Ketone)citations
- 2016Development of multifunctional complex fluids for coating of semi-porous surfaces
- 2010An overview on 12-polyurethane:Synthesis, structure and crystallizationcitations
- 2005Electrochemistry of Surface-Grafted Stimulus-Responsive Monolayers of Poly(ferrocenyldimethylsilane) on Goldcitations
- 2004Electrochemically Induced Morphology and Volume Changes in Surface-Grafted Poly(ferrocenyldimethylsilane) Monolayerscitations
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article
Ion-Selective Ionic Polymer Metal Composite (IPMC) Actuator Based on Crown Ether Containing Sulfonated Poly(Arylene Ether Ketone)
Abstract
This study introduces the concept of ion selective actuation in polymer metal composite actuators, employing crown ether bearing aromatic polyether materials. For this purpose, sulfonated poly(arylene ether ketone) (SPAEK) and crown ether containing SPAEK with molar masses suitable for membrane preparation are synthesized. The synthesized polymers are characterized using Nuclear magnetic resonance (NMR) and fourier transform infrared spectroscopy (FTIR) spectroscopy, thermal gravimetric analysis (TGA), and differential scanning calorimetry (DSC). Ionic polymer metal composite (IPMC) actuators are fabricated by electroless chemical deposition of a platinum (Pt) layer on both sides of SPAEK and crown-ether containing SPAEK membranes, resulting in electrode layers of around 120 nm thickness. Actuation experiments demonstrate cation specific responses and bending degrees of the IPMC actuators. Incorporation of crown ether units in the polymer backbone results in an improved and ion-selective bending displacement compared with SPAEK actuators. S(25)C(50)PAEK actuators show an increased bending displacement of 28% for Na+ and 20% for K+ ions.