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Publications (7/7 displayed)
- 2020Thermochromism of highly luminescent photopolymer flexible films based on Eu (III) salts confined in polysulfonecitations
- 2017Membranes with a low loading of Metal–Organic Framework-Supported Ionic Liquids for CO2/N2 separation in CO2 capturecitations
- 2014Metal-Organic frameworks based on uranyl and phosphonate ligandscitations
- 2013Preparation of dense 13C pellets using spark plasma sintering technique
- 2009Amino acid-functionalized cyclopentadienyl molybdenum tricarbonyl complex and its use in catalytic olefin epoxidationcitations
- 2007A combined theoretical-experimental study of the inclusion of niobocene dichloride in native and permethylated β-cyclodextrinscitations
- 2006Structural studies of [CpMoL2(CO)2]+ (L = NCMe, L2 = 2,2′-biimidazole) complexes and their inclusion compounds with cyclodextrinscitations
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article
Membranes with a low loading of Metal–Organic Framework-Supported Ionic Liquids for CO2/N2 separation in CO2 capture
Abstract
<p>Immobilization of ionic liquids (ILs) into 3D metal–organic frameworks (MOFs) is reported. The incorporation of these composites in a polyimide-based matrix (Matrimid® 5218) to yield [IL@MOF]@Matrimid® 5218 is an efficient strategy to improve the permeability and selectivity toward CO<sub>2</sub>/N<sub>2</sub> mixtures, presenting also a remarkable improvement in membrane flexibility and mechanical resistance. Using MOF-5, a crystalline phase different to its original phase is obtained after the incorporation of hydrated IL without loss of adsorptive properties.</p>