| People | Locations | Statistics |
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Muller, Hermance |
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| Kočí, Jan | Prague |
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| Šuljagić, Marija |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Ospanova, Alyiya |
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| Blanpain, Bart |
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| Ali, M. A. |
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| Popa, V. |
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| Rančić, M. |
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| Ollier, Nadège |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Bjerrum, Niels Janniksen
Technical University of Denmark
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (25/25 displayed)
- 2022Pressurized solid phosphate electrolyzer for medium temperature water splittingcitations
- 2020CsH2PO4 as Electrolyte for the Formation of CH4 by Electrochemical Reduction of CO2citations
- 2016Amino-Functional Polybenzimidazole Blends with Enhanced Phosphoric Acid Mediated Proton Conductivity as Fuel Cell Electrolytescitations
- 2014Hydrogen evolution activity and electrochemical stability of selected transition metal carbides in concentrated phosphoric acidcitations
- 2014The Chemical Vapour Deposition of Tantalum - in long narrow channels
- 2014Intermediate Temperature Steam Electrolysis with Phosphate-Based Electrolytes
- 2014Development of Non-Platinum Catalysts for Intermediate Temperature Water Electrolysis
- 2014Invited: A Stability Study of Alkali Doped PBI Membranes for Alkaline Electrolyzer Cells
- 2014High Surface Area Tungsten Carbides: Synthesis, Characterization and Catalytic Activity towards the Hydrogen Evolution Reaction in Phosphoric Acid at Elevated Temperatures
- 2013Catalyst Degradation in High Temperature Proton Exchange Membrane Fuel Cells Based on Acid Doped Polybenzimidazole Membranescitations
- 2013Development and Study of Tantalum and Niobium Carbides as Electrocatalyst Supports for the Oxygen Electrode for PEM Water Electrolysis at Elevated Temperaturescitations
- 2012Nickel and its alloys as perspective materials for intermediate temperature steam electrolysers operating on proton conducting solid acids as electrolyte
- 2012WC as a non-platinum hydrogen evolution electrocatalyst for high temperature PEM water electrolyserscitations
- 2012Development of Refractory Ceramics for The Oxygen Evolution Reaction (OER) Electrocatalyst Support for Water Electrolysis at elevated temperaturescitations
- 2011Corrosion behaviour of construction materials for high temperature steam electrolyserscitations
- 2011New Construction and Catalyst Support Materials for Water Electrolysis at Elevated Temperatures
- 2011Oxidative degradation of polybenzimidazole membranes as electrolytes for high temperature proton exchange membrane fuel cellscitations
- 20101.7 nm Platinum Nanoparticles: Synthesis with Glucose Starch, Characterization and Catalysiscitations
- 2010Strategic surface topographies for enhanced lubrication in sheet forming of stainless steelcitations
- 2007Corrosion monitoring in a straw-fired power plant using an electrochemical noise probecitations
- 2005Electrochemical noise measurements of steel corrosion in the molten NaCl-K2SO4 systemcitations
- 2004Development of strategic surface topographies for lubrication in sheet forming of stainless steel
- 2001Phosphoric acid doped polybenzimidazole membranes: Physiochemical characterization and fuel cell applications [PEM fuel cells]
- 2000On the chemical nature of boundary lubrication of stainless steel by chlorine - and sulfur-containing EP-additivescitations
- 2000Cold Forging of Stainless Steel with FeCl3 based lubricants
Places of action
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article
1.7 nm Platinum Nanoparticles: Synthesis with Glucose Starch, Characterization and Catalysis
Abstract
Monodisperse platinum nanoparticles (PtNPs) were synthesized by a green recipe. Glucose serves as a reducing agent and starch as a stabilization agent to protect the freshly formed PtNP cores in buffered aqueous solutions. Among the ten buffers studied, 2-(N-morpholino)ethanesulfonic acid (MES), ammonium acetate and phosphate are the best media for PtNP size control and fast chemical preparation. The uniform sizes of the metal cores were determined by transmission electron microscopy (TEM) and found to be 1.8 +/- 0.5, 1.7 +/- 0.2 and 1.6 +/- 0.5 nm in phosphate, MES and ammonium acetate buffer, respectively. The estimated total diameter of the core with a starch coating layer is 5.8-6.0 nm, based on thermogravimetric analysis (TGA). The synthesis reaction is simple, environmentally friendly, highly reproducible, and easy to scale up. The PtNPs were characterized electrochemically and show high catalytic activity for reduction of dioxygen and hydrogen peroxide as well as for oxidation of dihydrogen. The PtNPs can be transferred to carbon support materials with little demand for high specific surface area of carbon. This enables utilization of graphitized carbon blacks to prepare well-dispersed Pt/C catalysts, which exhibit significantly improved durability in the accelerated aging test under fuel cell mimicking conditions.