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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Romani, Lidia
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (9/9 displayed)
- 2023Air- and water-stable and photocatalytically active germanium-based 2D perovskites by organic spacer engineeringcitations
- 2023Air- and water-stable and photocatalytically active germanium-based 2D perovskites by organic spacer engineeringcitations
- 2023Development of Semicoducting Materials for Photoelectrochemical Cells
- 2021Experimental Strategy and Mechanistic View to Boost the Photocatalytic Activity of Cs3Bi2Br9 Lead‐Free Perovskite Derivative by g‐C3N4 Composite Engineeringcitations
- 2021Water‐Stable DMASnBr3 Lead‐Free Perovskite for Effective Solar‐Driven Photocatalysiscitations
- 2021g-C3N4/metal halide perovskite composites as photocatalysts for singlet oxygen generation processes for the preparation of various oxidized synthonscitations
- 2021Application of metal halide perovskites as photocatalysts in organic reactionscitations
- 2021Water-Stable DMASnBr3 Lead-Free Perovskite for Effective Solar-Driven Photocatalysiscitations
- 2020Carbon nitride-perovskite composites: Evaluation and optimization of photocatalytic hydrogen evolution in saccharides aqueous solutioncitations
Places of action
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article
Water‐Stable DMASnBr3 Lead‐Free Perovskite for Effective Solar‐Driven Photocatalysis
Abstract
<jats:title>Abstract</jats:title><jats:p>Water‐stable metal halide perovskites could foster tremendous progresses in several research fields where their superior optical properties can make differences. In this work we report clear evidence of water stability in a lead‐free metal halide perovskite, namely DMASnBr<jats:sub>3</jats:sub>, obtained by means of diffraction, optical and X‐ray photoelectron spectroscopy. Such unprecedented water‐stability has been applied to promote photocatalysis in aqueous medium, in particular by devising a novel composite material by coupling DMASnBr<jats:sub>3</jats:sub> to g‐C<jats:sub>3</jats:sub>N<jats:sub>4</jats:sub>, taking advantage from the combination of their optimal photophysical properties. The prepared composites provide an impressive hydrogen evolution rate >1700 μmol g<jats:sup>−1</jats:sup> h<jats:sup>−1</jats:sup> generated by the synergistic activity of the two composite costituents. DFT calculations provide insight into this enhancement deriving it from the favorable alignment of interfacial energy levels of DMASnBr<jats:sub>3</jats:sub> and g‐C<jats:sub>3</jats:sub>N<jats:sub>4</jats:sub>. The demonstration of an efficient photocatalytic activity for a composite based on lead‐free metal halide perovskite in water paves the way to a new class of light‐driven catalysts working in aqueous environments.</jats:p>