693.932 PEOPLE
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| Naji, M. |
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| Motta, Antonella |
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| Aletan, Dirar |
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| Mohamed, Tarek |
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| Ertürk, Emre |
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| Taccardi, Nicola |
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| Kononenko, Denys |
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| Petrov, R. H. | Madrid |
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| Alshaaer, Mazen | Brussels |
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| Bih, L. |
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| Casati, R. |
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| Kočí, Jan | Prague |
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| Kalteremidou, Kalliopi-Artemi | Brussels |
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| Azam, Siraj |
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| Azevedo, Nuno Monteiro |
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| Landes, Michael |
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| Rignanese, Gian-Marco |
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Feng, Xinliang
European Commission
in Cooperation with on an Cooperation-Score of 37%
Topics
Publications (58/58 displayed)
- 2024Impact of Thermal Annealing on the Dissolution of Semiconducting Polymer Thin Filmscitations
- 2024Venice’s macroalgae-derived active material for aqueous, organic, and solid-state supercapacitorscitations
- 2024Coexistence of Redox‐Active Metal and Ligand Sites in Copper‐based 2D Conjugated Metal‐Organic Frameworks for Battery‐Supercapacitor hybrid systemscitations
- 2024Mimicking on-water surface synthesis through micellar interfacescitations
- 2023Tailoring the Morphology of a Diketopyrrolopyrrole-based Polymer as Films or Wires for High-Performance OFETs using Solution Shearingcitations
- 2023On-water surface synthesis of electronically coupled 2D polyimide-MoS2 van der Waals heterostructurecitations
- 2023On-surface synthesis and characterization of teranthene and hexanthene: ultrashort graphene nanoribbons with mixed armchair and zigzag edgescitations
- 2023Curved graphene nanoribbons derived from tetrahydropyrene-based polyphenylenes via one-pot K-region oxidation and Scholl cyclizationcitations
- 2023Tunable Crystallinity and Electron Conduction in Wavy 2D Conjugated Metal–Organic Frameworks via Halogen Substitutioncitations
- 2023Hybrid aeromaterials for enhanced and rapid volumetric photothermal response
- 2023Piezo‐Phototronic In2Se3 Nanosheets as a Material Platform for Printable Electronics toward Multifunctional Sensing Applicationscitations
- 2023Near IR Bandgap Semiconducting 2D Conjugated Metal‐Organic Framework with Rhombic Lattice and High Mobilitycitations
- 2022Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworkscitations
- 2022Combination of Knoevenagel Polycondensation and Water-Assisted Dynamic Michael-Addition-Elimination for the Synthesis of Vinylene-Linked 2D Covalent Organic Frameworkscitations
- 2021Microengineered Hollow Graphene Tube Systems Generate Conductive Hydrogels with Extremely Low Filler Concentrationcitations
- 2021Multiscale Modeling Strategy of 2D Covalent Organic Frameworks Confined at an Air–Water Interfacecitations
- 2020Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditionscitations
- 2020Polycyclic aromatic chains on metals and insulating layers by repetitive [3+2] cycloadditionscitations
- 2020Near–atomic-scale observation ofgrain boundaries inalayer-stacked two-dimensional polymercitations
- 2020Production and processing of graphene and related materials
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materialscitations
- 2020Production and processing of graphene and related materials
- 2020Wetting Properties of Graphene Aerogelscitations
- 2020Two-Dimensional Boronate Ester Covalent Organic Framework Thin Films with Large Single Crystalline Domains for a Neuromorphic Memory Devicecitations
- 2020Highly selective and ultra-low power consumption metal oxide based hydrogen gas sensor employing graphene oxide as molecular sievecitations
- 2020Highly selective and ultra-low power consumption metal oxide based hydrogen gas sensor employing graphene oxide as molecular sievecitations
- 2020Highly crystalline and semiconducting imine‐based two‐dimensional polymers enabled by interfacial synthesis
- 2019Engineering crystalline quasi-two-dimensional polyaniline thin film with enhanced electrical and chemiresistive sensing performancescitations
- 2019On-surface synthesis of nitrogen-doped nanographenes with 5–7 membered ringscitations
- 2019Beyond Activated Carbon: Graphite‐Cathode‐Derived Li‐Ion Pseudocapacitors with High Energy and High Power Densitiescitations
- 2019Electrochemically Exfoliated High-Quality 2H-MoS<sub>2</sub> for Multiflake Thin Film Flexible Biosensorscitations
- 2019On‐surface synthesis and characterization of acene‐based nanoribbons incorporating four‐membered ringscitations
- 2019Topological defect-induced magnetism in a nanographenecitations
- 2019Fully sp2‐Carbon‐Linked Crystalline Two‐Dimensional Conjugated Polymers: Insight into 2D Poly(phenylenecyanovinylene) Formation and its Optoelectronic Propertiescitations
- 2018Engineering of robust topological quantum phases in graphene nanoribbonscitations
- 2018The mechanochemical Scholl reaction – a solvent-free and versatile graphitization toolcitations
- 2017Persulfurated Coronene: A New Generation of "Sulflower"citations
- 2017A Stable Saddle-Shaped Polycyclic Hydrocarbon with an Open-Shell Singlet Ground Statecitations
- 2017Revealing the electronic structure of silicon intercalated armchair graphene nanoribbons by scanning tunneling spectroscopycitations
- 2017Coordination Polymer Framework Based On-Chip Micro-Supercapacitors with AC Line-Filtering Performancecitations
- 2017Polycyclic heteroaromatic hydrocarbons containing a benzoisoindole corecitations
- 2017Monitoring the on-surface synthesis of graphene nanoribbons by mass spectrometrycitations
- 2016Synthesis of Graphene Nanoribbons by Ambient-Pressure Chemical Vapor Deposition and Device Integrationcitations
- 2016On-surface synthesis of graphene nanoribbons with zigzag edge topologycitations
- 2016Synthesis of NBN-Type Zigzag-Edged Polycyclic Aromatic Hydrocarbons: 1,9-Diaza-9a-boraphenalene as a Structural Motifcitations
- 2015Toward cove-edged low band gap graphene nanoribbonscitations
- 2014Squeezing, Then Stacking: From Breathing Pores to Three-Dimensional Ionic Self-Assembly under Electrochemical Controlcitations
- 2013Termini of bottom-up fabricated graphene nanoribbonscitations
- 2012Nitrogen-Doped Graphene and Its Iron-Based Composite As Efficient Electrocatalysts for Oxygen Reduction Reactioncitations
- 2010Self-assembling thiophene dendrimers with a hexa-peri-hexabenzocoronene core- synthesis, characterization and performance in bulk heterojunction solar cellscitations
- 2009Self-assembling thiophene dendrimers with a hexa-peri-hexabenzocoronene core- synthesis, characterization and performance in bulk heterojunction solar cells
- 2008Molecular clusters in two-dimensional surface-confined nanoporous molecular networks: structure, rigidity, and dynamicscitations
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article
Impact of Thermal Annealing on the Dissolution of Semiconducting Polymer Thin Films
Abstract
<p>Here, the effect of thermal annealing (TA) on the stability of solution-sheared thin films of the semiconducting polymer poly[2,5-bis(2-octyldodecyl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione-3,6-diyl)-alt-(2,2′;5′,2′’;5′’,2′’’-quaterthiophen-5,5′’’-diyl)] (PDPP4T) against the original coating solvent is studied, and it is shown that TA significantly improves the solvent resistance of semiconducting polymer films. Specifically, after the thin films are annealed at or above a critical temperature, the thin film thickness is largely retained when exposed to the original solvent, while for lower annealing temperatures material loss occurs, i.e., the thin film thickness is reduced due to rapid dissolution. The results of various techniques including grazing-incidence wide-angle x-ray scattering (GIWAXS), atomic force microscopy (AFM), and ultraviolet-visible-near infrared (UV–vis-NIR) absorption spectroscopy suggest physical changes as the cause for the increased solvent resistance. Such annealed films also show stable electrical characteristics in bottom-gate, top-contact (BGTC) organic field-effect transistors (OFETs) even after solvent exposure. In initial tests, a multitude of technologically relevant polymers show such behavior, underlining the potential impact of such temperature treatments for the fabrication of multi-layer polymer devices.</p>