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Naji, M. |
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Motta, Antonella |
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Aletan, Dirar |
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Mohamed, Tarek |
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Ertürk, Emre |
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Taccardi, Nicola |
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Kononenko, Denys |
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Petrov, R. H. | Madrid |
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Alshaaer, Mazen | Brussels |
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Bih, L. |
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Casati, R. |
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Muller, Hermance |
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Kočí, Jan | Prague |
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Šuljagić, Marija |
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Kalteremidou, Kalliopi-Artemi | Brussels |
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Azam, Siraj |
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Ospanova, Alyiya |
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Blanpain, Bart |
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Ali, M. A. |
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Popa, V. |
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Rančić, M. |
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Ollier, Nadège |
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Azevedo, Nuno Monteiro |
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Landes, Michael |
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Rignanese, Gian-Marco |
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Bendounan, Azzedine
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Topics
Publications (15/15 displayed)
- 2023Dirac Fermions in Blue Phosphorene Monolayercitations
- 2023Dirac Fermions in Blue Phosphorene Monolayercitations
- 2023First steps of silicene growth on an insulating thin-film: effect of the substrate temperature
- 2023First steps of silicene growth on an insulating thin-film: effect of the substrate temperature
- 2021MoS2/PPy Nanocomposite as a Transducer for Electrochemical Aptasensor of Ampicillin in River Water
- 2021MoS2/PPy Nanocomposite as a Transducer for Electrochemical Aptasensor of Ampicillin in River Watercitations
- 2021Electron beam analysis induces Cl vacancy defects in a NaCl thin filmcitations
- 2020Evidence of new 2D material: Cu<sub>2</sub>Tecitations
- 2020Phosphorus Pentamers: Floating Nanoflowers form a 2D Networkcitations
- 2020Single-layer graphene on epitaxial FeRh thin filmscitations
- 2020Phase transition and thermal stability of epitaxial PtSe 2 nanolayer on Pt(111)citations
- 2020Evidence of new 2D material: Cu 2 Tecitations
- 2017Giant Rashba effect at the topological surface of PrGe revealing antiferromagnetic spintronicscitations
- 2016Case studies on the formation of chalcogenide self-assembled monolayers on surfaces and dissociative processescitations
- 2012Monitoring the formation of interface-confined mixture by photoelectron spectroscopycitations
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article
Phosphorus Pentamers: Floating Nanoflowers form a 2D Network
Abstract
We present an experimental investigation of a new polymorphic 2D single layer of phosphorus on Ag(111). The atomically-resolved scanning tunneling microscopy (STM) images show a new 2D material composed of freely-floating phosphorus pentamers organized into a 2D layer, where the pentamers are aligned in close-packed rows. The scanning tunneling spectroscopy (STS) measurements reveal a semiconducting character with a band gap of 1.20 eV. This work presents the formation at low temperature (LT) of a new polymorphic 2D phosphorus layer composed of a floating 2D pentamer structure. The smooth curved terrace edges and a lack of any clear crystallographic orientation with respect to the Ag(111) substrate at room temperature indicates a smooth potential energy surface that is reminiscent of a liquid-like growth phase. This is confirmed by density functional theory (DFT) calculations that find a small energy barrier of only 0.17 eV to surface diffusion of the pentamers (see Supplemental Material). The formation of extended, homogeneous domains is 2 a key ingredient to opening a new avenue to integrate this new 2D material into electronic devices.